Physical Chemistry exam paper 2011-I.docVIP

浙江工业大学20 / 2011（2）学年 物理化学（D）期终考试A卷班级___________ 姓名__________ 学号___________任课教师_____________ 注意：答案一律写在答卷纸上，否则无效、1、When a perfect gas s into a vacuumed (真空的) thermal-insulated (绝热的) container, its temperature will (a) increase. 　(b) decrease. (c) not change. (d) be uncertain. 2、’ law involves these 2 important problems: The 1st and 3rd law of thermodynamics(热力学). The 1st law of thermodynamics and the basic properties of heat. The 3rd law of thermodynamics and the basic properties of heat. The 1st law of thermodynamics and the basic characteristics of state functions (状态函数). 3、ΔH＝QpPa constant external pressure, and the gas pressure changes from 101325 Pa to 10132.5Pa. A sample of ice melts into water at 0℃, 101325Pa. A sample of CuSO4 solution (溶液) undergoes electrolysis (电解).　 A gas reversibly (可逆地) changes from its initial (初始) state (298K, 101325Pa) to a final state (373K, 10132.5Pa). 　　 4、焦耳-汤姆系数μ is not always 0. For a non-perfect (非理想) gas, its Joule-Thompson coefficient μ can never be 0. Perfect gas cannot be used as the working media (工作介质) of refrigerators (冰箱). For a non-perfect gas, there’s only one (p, T) state at which Joule-Thompson coefficient μ is 0. 5、thermally insulated (绝热的) rigid (刚性的) container is divided into 2 parts which contain air (considered as perfect gas) with different pressures. If p右 p左 （a） Q ＝0, W ＝0, △U ＝0 （b） Q＝0, W 0, ?△U 0 （c） Q 0, W 0, ?△U 0 （d）△U ＝0, Q＝W ?0 、’t. Both the system and its surroundings have no change. 7、(S means The sum of heat–temperature quotients (热温商) in irreversible (不可逆) processes. The sum of heat–temperature quotients in reversible (可逆) processes. A state function (状态函数) change which has no relation with paths (路径). A state function change which has relation with paths. The correct descriptions above are: (a) 1, 2 (b) 2, 3 (c) 2 (d) 4 8、（a） （b） 　（c） （d） 9、((U/(S)V is equal to (a) ((H/(S)p