用于低表面能材料的UV胶粘剂.docVIP

UV Curable silicone adhesive for difficult to bond materials HAO Jianqiang and HARA Osamu Abstract A UV curable silicone composition was developed which was comprised of an addition reaction product of amino-terminated organopolysiloxane and a vinyl group-containing isocyanate, an acrylic ester monomer and a photoinitiator. The composition can be cured by UV to tough elastomers and showed excellent adhesion to difficult to bond materials such as PE, PP, PET, polyolefin, etc. without need of any pretreatment of the surfaces. The compositions were transparent and found useful as elastomeric adhesives, potting and sealing agents. Ultraviolet curing (UV), Difficult to bond, Polypropylene (PP), Polyethylene (PE), Poly(ethylene terephthalate) (PET), Silicone, Acrylic ester, Sealing, Potting, Adhesive, Adhesion 1. INTRODUCTION Polyethylene (PE), polypropylene (PP), and poly (ethylene terephthalate) (PET) are most widely used plastics in modern society and received much more attention today due to their harmony with the environment and ease of recycle. The unit assembly or adhesion of these plastics such as laminating are often encountered, however, it is known in the art they are difficult to bond with each other by adhesives because of their low surface energy, low polarity, and little or no porosity. To improve the adhesion of these materials, surface treatments, such as plasma treatment, corona discharge, chemical oxidation, and primer coating have been used to alter the surface. But these treatments are expensive and time consuming, and are not always possible. In applications concerned with these difficult to bond materials, hot melt adhesive, cyanoacrylate with primer system, two-component epoxy resin, and two-component acrylate adhesive have been developed. But these systems are still not satisfactory to meet the needs of high speed line requirement. Primer treatment or premixing handling for two-component systems is also negative factors in practical a