第十讲平衡级分离过程.pptVIP

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第十讲平衡级分离过程

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * Single Equilibrium Stages Ternary Liquid-Liquid Systems (3) Single Equilibrium Stages Ternary Liquid-Liquid Systems (4) Single Equilibrium Stages Ternary Liquid-Liquid Systems (5) Single Equilibrium Stages Ternary Liquid-Liquid Systems (6) Single Equilibrium Stages Ternary Liquid-Liquid Systems (7) Single Equilibrium Stages Ternary Liquid-Liquid Systems (8) Single Equilibrium Stages Multicomponent Liquid-Liquid Systems For multicomponent liquid-liquid systems, manual calculations based on phase diagrams are impossible. The computation of the equilibrium phase compositions is best made by a computer-assisted algorithm using activity coefficient equations such as NRTL or UNIQUAC equations. An effective algorithm is a modified Rachford-Rice procedure. Multicomponent Liquid-Liquid Systems Solid-Liquid Systems Leaching In a leaching operation, a multi-component solid mixture is separated by contacting the solid with a solvent that selectively dissolves some, but not all, components in the solid. A leaching stage is shown in the figure. Leaching The left row Ideal leaching conditions. The right row nonideal leaching conditions. Solid-Liquid Systems Crystallization Usually, crystallization are carried out by reducing the temperature of a solution or vaporizing the solvent. The solid-liquid phase equilibria behavior is very complicated. Several kinds of crystals may result at different or the same temperatures. The basis for crystallization calculation is mainly on the phase diagrams experimentally measured. Solid-Liquid Systems Crystallization Solid-Liquid Systems Crystallization Vapor-Liquid-Liquid Systems 3-Phase Flash Vapor-Liquid-Liquid Systems 3-Phase Flash-Example 4.19 * * * * * * * * * * * * * * * * * First page 传递过程 与 分离技术 全日制专业硕士研究生学位课程 面向应用的 专业基础课程 第十讲—平衡级分离过程 i10.1 单级分离过程 Flash Calculation and Introduction The separation process by single equilibrium stage is one in which two phase i

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