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Rheological properties of aqueous solution containing xanthan gum and cationic cellulose JR400.docx

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Rheological properties of aqueous solution containing xanthan gum and cationic cellulose JR400

CarbohydratePolymers90(2012)1330–1336ContentslistsavailableatSciVerseScienceDirectCarbohydratePolymersjournalhomepage:/locate/carbpolRheologicalpropertiesofaqueoussolutioncontainingxanthangumandcationiccelluloseJR400HaipingLia,RenfuChenb,XiaomeiLua,WanguoHoua,?aKeyLaboratoryforColloidandInterfaceChemistryofEducationMinistry,ShandongUniversity,Jinan250100,PRChinabCollegeEntranceExaminationTutorialSchoolsofAnqiuCity,Anqiu262100,PRChinaarticleinfoabstractArticlehistory:Received23May2012Receivedinrevisedform25June2012Accepted2July2012Availableonline10July2012Rheologicalpropertiesofaqueoussolutioncontainingxanthangum(XG)andcationiccelluloseJR400wereinvestigatedatdifferentcompositionratio,shearrate,pHandelectrolyteconcentrations.ItwasfoundthatthemixingofXGandJR400caninduceaviscosity-increasingeffectforthemixedsolution.Astheconcentrationfraction(fJR)ofJR400inthemixedsolutionincreasesfrom0to0.40withthetotalpolymerconcentration(ct)of1%,thesolutiontransformsfromanelastic?uidintoaviscoelasticone,whileasfJRdecreasesfrom1to0.78,thesolutiontransformsfromaviscous?uidintoaviscoelasticone.Keywords:ElectrostaticattractionAtpH5–10,boththeviscosityandelasticityofXG/JR400mixture(fJR=0.15)areindependentofpHandXanthangumJR400ShearratepHElectrolytetheviscosity-increasingeffectisobvious.OutsidethispHrange,theviscosity,elasticityandviscosity-increasingeffectofthemixturedecrease.TheincreaseofaddedNaClconcentrationandshearratecaninducethedecreaseofviscosity,elasticityandviscosity-increasingeffectoftheXG/JR400mixture.?2012ElsevierLtd.Allrightsreserved.IntroductionPolyelectrolytecomplexes(PECs)canbeformedviatheelec-trostaticinteractionbetweenpolyanionsandpolycations(FuossSadek,1949;MichaelsMiekka,1961;Michaels,Mir,Schneider,1965).SincetheearlyworkonPECsbyFuossandSadek(1949)andbyMichaelsandMiekka(1961),lotsofstudiesandreviewshavebeenpublishedinthis?eld(Al-Jamal,Ramaswamy,Florence,2005;K?tz,Kosmella,Beitz,2001;KabanovKabanov,1998;Kabanov,2005;Michaels,1965;Thünemann,Müller,Dautzenberg,Joanny,L?wen