材料科学基础07-相图-2.pptVIP

Determination of Compositions on Ternary Diagram Determination of Compositions on Ternary Diagram 3-D Ternary Phase Diagram 3-D Ternary Phase Diagram Projection of 3-D Diagram to 2-D Diagram Simple Ternary Phase Diagram Crystallization Paths 析晶路线 Determination of Amounts of Phases Ternary Diagrams with an congruent Binary Compound Ternary Diagrams with Congruent Binary Compounds Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with a Binary Compound Ternary Diagrams with Congruent Binary Compounds Ternary Diagrams with a Ternary Compound Ternary Diagrams with a Ternary Compound Ternary Diagrams with a Ternary Compound Assignment 4 Assignment 5 * Overall composition （总组成）: X Content A (%) = 20 Content B (%) = 40 Content C (%) = 40 Ternary diagram: 三元相图 Overall composition: Y Content A (%) = 20 Content B (%) = 40 Content C (%) = 40 Composed of three binary systems System A-B System B-C System A-C Liquidus line Liquidus surface Eutectic point Eutectic boundary line Ternary eutectic point Base triangle 等温线 Ternary phase diagram without binary or ternary compounds Temperature goes down Liquid + A Liquid + B Liquid + C Liquid + B + C Liquid + A +C Liquid + A + B Liquid + A + B + C ? X 1’ 2’ 2” 3” Overall composition X T3: liquid only T3 – T4: liquid only T4: B begins to precipitate 析出 T4 – T5: L ? B T5: A and B co-precipitate T5 – TE: L ? A + B TE: L ? A + B + C Composition of liquid: Composition of solid: X ? 1’ ? 2’ ? E B ? 2” ? 3” ? X ? X 1’ 2’ 2” 3” Overall composition X Temperature reaches T2’ Lever Rule Congruently melting binary compound AB Two ternary diagrams: Sub-system B-C-AB Sub-system C-A-AB Congruently melting binary compound Al2TiO5 Three ternary diagrams: Sub-system Al2O3-ZrO2- Al2TiO5 Sub-system ZrO2- Al2TiO5-ZrTiO4 Sub-system TiO2- Al2TiO5-ZrTiO4 Th