分光光度法研究JFC在煤尘表面的吸附行为.docVIP

分光光度法研究JFC在煤尘表面的吸附行为 杨静;王振华;谭允祯;商岩冬; 摘要： 提出了用KI-I2做显色剂的分光光度法测定非离子表面活性剂JFC浓度的新方法。实验表明,该方法的最佳实验条件是测定波长为510 nm,显色时间为30 min,工作曲线线性相关系数为0.999 3。该方法显色迅速、工作曲线线性相关性好、试剂易得、操作简单,利用该方法研究了JFC在煤尘表面的吸附行为。研究发现,在稀溶液范围内,JFC在上煤样的吸附均符合Lang-muir等温方程,且吸附量的大小随挥发分的增加逐渐增大,随粒度的减小而逐渐增大。 关键词： 煤尘;;JFC;;吸附;;分光光度法 Abstract: The paper put forward the new method of using the spectrophotometry testing the concentration of nonionic surfactant with KI-I_2 chromogenic agent.The experiment shows that the best testing wavelength is 510nm,the time of chromogenic reaction is 30min and the correlation coefficient of the standard curve is 0.9993.As the chromogenic reaction is quick,the correlation coefficient approach to 1 and the reagent is easy to get,it is obvious to use this method to study on the absorption behavior of JFC on the surface of coal dust.The absorption is in accord with Langmuir isothermal equation,the smaller coal with higher volatile can absorpt more surfactant. Keywords: coal dust;JFC;absorption;spectrophotography 收稿日期 2008-02-10 DOI: CNKI:SUN:MKAQ.0.2008-02-002 基金项目: 山东省科技攻关项目(2005GG3208105,2005GG3210003) 通讯作者: Email: 作者简介: 参考文献： [1]Gay;Frank T.;Cowsette.Method of dusting coal minesurfaces〔P〕.United States Patent:6726849,2004. [2]Roe;Donald C.;Chen.Methods for suppressing dust e-missions〔P〕,United States Patent:5648116,1997. [3]吴超,古德生.Na2SO4改善阴离子表面活性剂湿润煤尘性能的研究〔J〕.安全与环境学报,2001,1(2). [4]肖进新,赵振国.表面活性剂应用原理〔M〕.北京:化学工业出版社,2003:88-89. [5]CHANG J H,MAKOFO O,et al.Interaction of iodinewith nonionic surfactant and polyehtylene glycol in aque-ous potassium lodide solution〔J〕.J Am Oil Cherm,1988,65(10):1644-1668. [6]黄文,顾惕人.碘光谱法测定非离子表面活性剂的临界胶束浓度〔J〕.精细化工,1996,13(1):5-8.