chapter 9 Alcohol.pptVIP

Organic Chemistry 有机化学 Version 1.2 教材与推荐参考书 Chapter 9. Alcohol, phenol and ether ① 按与－OH相连的碳原子的类型分：伯、仲、叔醇。 Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether 以醇为母体。选择含有－OH的最长碳链为主 链，从靠近－OH的一端开始编号，把支链看成取代基。例： Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether 两个羟基都连在叔碳上的α-二醇称为频哪醇(pinacol)。 在酸性溶液中，频哪醇失去一分子水，重排得到不对称酮。 例如： Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether 按照官能团优先次序规则，选择母体。 Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether 醇和酚形成金属盐后，与卤代烃、硫酸二甲酯作用，生成相应的醚。 Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether Chapter 9. Alcohol, phenol and ether (1) 卤代反应 Chapter 9. Alcohol, phenol and ether (2) 磺化反应 Chapter 9. Alcohol, phenol and ether (3) 硝化反应 Chapter 9. Alcohol, phenol and ether (3) 硝化反应 Chapter 9. Alcohol, phenol and ether (4) Friedel – Crafts 反应 Chapter 9. Alcohol, phenol and ether (5) Fries 重排 Chapter 9. Alcohol, phenol and ether (6) 与羰基化合物的缩合反应 Chapter 9. Alcohol, phenol and ether (7) Kolbe – Schmidt 反应 Chapter 9. Alcohol, phenol and ether 在氧化剂作用下，酚被氧化成醌。例如： Chapter 9. Alcohol, phenol