高等有机化学-第七章不饱和碳杂键的加成反应资料.pptVIP

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2016-09-18 发布于湖北
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高等有机化学-第七章不饱和碳杂键的加成反应资料.ppt

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* 16-27 Addition of Conjugated Alkenes to Aldehydes (the Baylis–Hillman Reaction) 16-28 The Reformatsky Reaction 16-29 The Conversion of Carboxylic Acid Salts to Ketones with Organometallic Compounds 16-30 The Addition of Organometallic Compounds to CO2 and CS2 16-31 The Addition of Organometallic Compounds to CN Compounds 16-32 Addition of Carbenes and Diazoalkanes to CN Compounds 16-33 The Addition of Grignard Reagents to Nitriles and Isocyanates G. Carbon Attack by Active Hydrogen Compounds 16-34 The Aldol Reaction 16-35 Mukaiyama Aldol and Related Reactions 16-36 Aldol-Type Reactions between Carboxylic Acid Derivatives and Aldehydes or Ketones 16-37 The Henry Reaction 16-38 The Knoevenagel Reaction 16-39 The Perkin Reaction 16-40 Darzens Glycidic Ester Condensation 16-41 The Peterson Alkenylation Reaction 16-42 The Addition of Active Hydrogen Compounds to CO2 and CS2 16-43 Tollens’ Reaction 16-44 The Wittig Reaction 16-45 Tebbe, Petasis and Alternative Alkenylations 16-46 The Formation of Epoxides from Aldehydes and Ketones 16-47 The Formation of Aziridines from Imines 16-48 The Formation of Episulfides and Episulfones 16-49 Cyclopropanation of Conjugated Carbonyl Compounds 16-50 The Thorpe Reaction H. Other Carbon or Silicon Nucleophiles 16-51 Addition of Silanes 16-52 The Formation of Cyanohydrins 16-53 The Addition of HCN to CN and CN Bonds 16-54 The Prins Reaction 16-55 The Benzoin Condensation * ADVANCED ORGANIC CHEMISTRY Part II Shanxi Normal University 2014 CHAPTER 7 Addition to Carbon–Hetero Multiple Bonds MECHANISM AND REACTIVITY Nucleophilic Substitution at an Aliphatic Trigonal Carbon: The Tetrahedral Mechanism 2. REACTIONS MECHANISMS 1.1 Nucleophilic Substitution at an Aliphatic Trigonal Carbon: The Tetrahedral Mechanism 2. REACTIONS A. Attack by OH (Addition of H2O) 7-1 The Addition of Water to Aldehydes and Ketones: Formation of H