selectedslidesfromin-classlecturesonirspectroscopy.pptVIP

* * * * * * * * * * * * * * * RAIRS To detect sub-monolayer coverages RAIRS, uses near grazing incidence geometry Optimum angle of incidence for RAIRS is 75 to 86? parallel polarization, depending on the properties of the surface. Fresenius J Anal Chem (1998) 362 : 15–20 RAIRS of PNBA as a function of angle of incidence. Greenler RG. 1966.J. Chem. Phys.44:310–15 RAIRS Surface Selection Rule The observation of vibrational modes of adsorbates on metallic substrates is subject to the surface dipole selection rule. This states that only those vibrational modes which give rise to an oscilla