11 醛和酮习参考答案.docVIP

11 醛和酮习题参考答案 1. 系统名称依次为：戊醛、2-戊酮、3-戊酮、3-甲基丁醛、2-甲基丁醛、3-甲基-2-丁酮、2,2-二甲基丙醛。 系统名称依次为：苯乙醛、苯乙酮、邻甲基苯甲醛、间甲基苯甲醛、对甲基苯甲醛。 2. 1 .苯甲酸 2 .苯甲酸 3 .苯甲酸 4 .苄醇 5 .苄醇 6 . 苄醇 7 . 二苯甲醇 8 . 9 . 10 . PhCH NOH 11 . PhCH NNHPh 12 . 13 . 3. 与 1 、 2 、 3 无反应，其它参照习题2 4. 1 苯乙酮 2 丁醛 6. 7. 8. 1 为动力学控制，取代基少的一端去质子反应速率快； 2 为热力学控制，共轭的且双键上取代基比较多结构相对比较稳定 见下图 。 9. 10. 11. 12. 13. 14. 15. 16. 17. integrated energy, chemicals and textile Yibin city, are the three core pillars of the industry. In 2014, the wuliangye brand value to 73.58 billion yuan, the citys liquor industry slip to stabilise. Promoting deep development of integrated energy, advanced equipment manufacturing industry, changning district, shale gas production capacity reached 277 million cubic metres, built the countrys first independent high-yield wells and pipelines in the first section, the lead in factory production and supply to the population. 2.1-3 GDP growth figure 2.1-4 Yibin, Yibin city, Yibin city, fiscal revenue growth 2.1.4 topography terrain overall is Southwest, North-Eastern State. Low mountains and hills in the city landscape as the main ridge-and-Valley, pingba small fragmented nature picture for water and the second land of the seven hills. 236 meters to 2000 meters above sea level in the city, low mountain, 46.6% hills 45.3%, pingba only 8.1%. 2.1.5 development of Yibin landscapes and distinctive feature in the center of the city, with limitations, and spatial structure of typical zonal group, 2012-cities in building with an area of about 76.2km2. From city-building situation, old town-the South Bank Center construction is lagging behind, disintegration of the old city is slow, optimization and upgrading, quality public service resources are still heavily concentrated in the old town together. Southbank Centre has not been formed, functions of the service area space is missing. Meanwhile, peripheral group centres service was weak and inadequate accounting for city development, suspicious pattern could