传质与分离习题文)钟理.docVIP

Problem for Mass Transfer and Separation Processes Absorption 1 At 20℃, the ammonia solubility in water is l0kgNH3／1000kgH2O, gas phase equilibrium molar fraction y* is 0.008, try to calculate following coefficients, Henry coefficient E, equilibrium constant m when the following conditions are (1) Total pressure above the ammonia is 101.3kPa (absolute atmosphere); (2) Total pressure above the ammonia is 301.9kPa (absolute atmosphere); 2 The ammonia–air mixture containing 9% ammonia (molar fraction) is contact with the ammonia-water liquid containing 5% ammonia (molar fraction). Under this operating condition, the equilibrium relationship is y*=0.97x. When the above two phases are contact, what will happen, absorption or stripping? 3 When the temperature is 10 oC and the overall pressure is 101.3KPa , the solubility of oxygen in water can be represented by equation p=3.27(104x, where p (atm) and x refer to the partial pressure of oxygen in the vapor phase and the mole fraction of oxygen in the liquid phase, respectively. Assume that water is fully contact with the air under that condition, calculate how much oxygen can be dissolved in per cubic meter of water? 4 An acetone-air mixture containing 0.02 molar fraction of acetone is absorbed by water in a packed tower in countercurrent flow. 99％ of acetone is removed when mixed gas molar flow rate is 0.03kmol·s-1m-2 and practice absorbent flow rate L is 1.4 times as much as the min amount required. Under the operating condition, the equilibrium relationship is y*=1.75x, volume total absorption coefficient is Kya=0.022 kmol·s-1m-2y-1.. What is the molar flow rate of the absorbent and how height of packing will be required? 5 The mixed gas from an oil distillation tower contains H2S=0.04(molar fraction). Triethanolamine (三乙醇胺) is used as the absorbent to remove 99% H2S in the packing tower, the equilibrium relationship is y*=1.95x, the molar flux rate of the mixed gas is 0.02kmol·m-2·s-1，volume