农林废料应用於固态生质燃料砖制造之研究.docVIP

農林廢料應用於固態生質燃料磚製造之研究 The Manufacture of Solid Biomass Fuel Briquettes using Agro-forestry Wastes 研究生：劉任卿 Liu, Jen-Ching 指導教授：林曉洪 Lin, Sheau-Horng 【摘要】 本研究之目的探討種回收自農林產業之廢，經固化處理後，製造固生質燃料磚固生質燃料炭磚，其炭化前後熱值之效應等相性質後，以作為能源應用 之參考。六種農林廢料中，三種木質類（廢棄太空包、亞麻粒片板、稻稈）之可燃份介於74~79 %碳氫化學元素含量61~66 %；三種紙漿污泥（紙漿污泥、紙渣污泥、綠泥）之可燃份介於83~88 %碳氫化學元素含量20~ %。 廢棄太空包綠泥稻稈亞麻粒片板紙漿污泥、紙渣污泥固態生質燃料磚吸水量以三種紙漿污泥類者最高，而三種木質類者較低。其中以綠泥固態燃料磚者最大，而廢棄太空包者最小。固態生質燃磚硬度及抗壓強度皆以三種木質類者較高，而三種紙漿污泥類者較低。 固態生質燃料炭磚之炭收率隨著炭化溫度及持溫時間增加，而呈顯著下降。低溫炭化（300 ℃）炭收率高於高溫炭化者（900 ℃）。又其灰分pH值隨著炭化溫度增加而增加；至於體積收縮率（VSP）及密度損失率（DLP）亦隨炭化溫度及持溫時間增加而增大，尤以高溫炭化者最為顯著。炭化溫度增加而增加；兩者間呈一次直線迴歸顯著正相關。相同炭化溫度時，亦會隨著持溫時間增加而提高其熱值。 固態生質燃炭磚之熱值效應（EHV）（25.1~112.6 %）、亞麻粒片板廢料（48.2~105.6 %）、稻稈（25.0~145.3 %）、紙漿污泥（7.6~106.3 %）、紙渣污泥（7.8~127.8 %）及綠泥（3.8~127.8 %）。且900 ℃（105.3 MJ/kg）＞700 ℃（79.95 MJ/kg）＞500 ℃（52.7 MJ/kg）＞300℃（26.8 MJ/kg）。生質fter solidification processing, the manufacture of solid biomass fuel briquette and their related properties were examined, and then by charcoalization to manufacture solid biomass fuel charcoalized briquette. Estimation their heating values efficiency of before and after charcoalization . Application feasibility of reference as the manufactured solid biomass energy technology and application in the future. The results showed that the combustible matters （CM）three kinds of wooden wastes cultivation waste bag, flaxboard and rice straw for 74-89 %, their carbon and hydrogen chemical elemental content was 61-66 %, and the VCM of three kinds of pulp sludge pulp sludge, paper rejects sludge and dregs were 83-88 %, and their carbon and hydrogen chemical elemental content was 20-45 %, respectively. The springback ratio of solid biomass fuel briquette because stable state within five days later. Dregs had a greatest of springback ratio, and the other five were same values. The springback ratio of cultivation waste bag, dregs, and rice straw showed the biggest in thickness direction, while flaxboard, pulp sludge, and paper rejects sludge were in width dir