可燃性固体废弃物及其二元混合物焚化之发热模式研究.docVIP

可燃性固體廢棄物及其二元混合物焚化之發熱模式研究 A Study on Combustion Heats of Combustible Solid Wastes and Their Binary Mixtures 研究生：鄭云淳 指導教授：李嘉塗 【摘要】 每單位垃圾重所產生的熱值，也就是發熱量，包括高位發熱量 High Heating Value，HHV 以及低位發熱量 Low Heating Value，LHV 。垃圾的低位發熱量即為設計焚化處理設施時最重要的基本數據之一，其值之大小將直接影響到焚化設施之處理能力及其他相關設施的規模。西元2001年台灣地區約產生61129公噸廢塑膠製品，佔垃圾組成的21.10﹪。一般文獻中很少研究不同比率之純物質混合物及其發熱量的關係，因此本研究利用熱卡計進行發熱量實驗，將揭露不同可燃性固體廢棄物依特定比率混合後其發熱量的變化情形。以及利用Microsoft Visual Basic 6.0程式開發軟體建立發熱量經驗公式。由結果顯示大部分二元塑膠混合物燃燒其熱值變化均呈線性加成，PBT∕PET 、PP∕PS、PET/PVC、PEO/PVC與PPO/PVC系統會出現正偏差的現象，PP∕HDPE與PET∕PEO焚化系統，會有負偏差現象發生，紙類與塑膠二元物混合燃燒也會有正、負偏差現象發生。此結果可提供未來將垃圾中塑膠成分回收再製成高效能廢塑膠衍生燃料 Wasted Plastics Refuse Derived Fuel，WRDF 的設計參考。 關鍵字：廢塑膠、衍生燃料、發熱量 【Abstract】 Heating values including higher heating value and lower heating value mean the heats of combustion per unit weight of municipal solid wastes MSW . Lower heating value of MSW is a basic and important design parameter of incineration system. In 2001, about 61129 tons 21.10% of wasted plastics in MSW were found in Taiwan. However, it is rare to see relative literatures concerning the studies of the relationship between heating values and mixing ratios of pure matter. In this paper, authors will investigate the effect of mixing ration of plastics on the heating values of their mixtures. An empirical equation regarding elemental compositions of these pure matters will be obtained from a Microsoft Visual Basic 6.0 based program. Results point out that most binary mixture of plastics show a linear combination of their identical heating values. Furthermore, PBT/PET, PP/PS, PET/PVC, PEO/PVC and PPO/PVC show a positive deviation relation while PET/PEO and PP/HDPE show a negative deviation relation. Binary mixture of paper and plastic also shows a deviation from linear addition. Heating value behaviors of these pure matters could be a design parameter for preparing the wasted plastics refuses derived fuel, WRDF. Keywords：Wasted Plastics, Refuse Derived Fuel, Heating Value