类Fenton反应催化剂功能之评估.docVIP

類Fenton反應催化劑功能之評估Evaluation of a Fe/organic complex-based catalyst for modified-Fenton reaction 研究生：邱景暉 Chiou, Jing-Huei 指導教授：葉桂君陳庭堅 Chen Ting-Chien 【摘要】 有害物質在儲存或運輸時，因人為因素或意外造成污染物洩漏，污染物可能進入至土壤甚至流入地下水層。整治地下水層的工作會因深度較難快速進行。近年來使用化學氧化法整治受污染之地下水層都獲得不錯成效。Fenton法是利用Fe（II）為催化劑，催化H2O2產生．OH分解污染物，比單獨使用H2O2氧化效果好。過去利用Fenton法現地處理受污染地下水的確展現良好之去除率但是卻存在眾多缺點，因此以鐵化合物催化H2O2產生．OH之類Fenton法，可改善Fenton法需pH 2~3環境下進行。因此，近年來許多研究轉向開發液態複合鐵為Fenton-like反應之催化劑。本研究乃於實驗室評估某公司研發之Fe/有機酸複合鐵之Fenton-like催化劑。結果顯示，催化劑於酸性時，低濃度有重複催化能力，高濃度則無，且有沈澱物產生。催化劑在中性時，不論濃度高低都有重複催化能力，反應後不會生成沈澱物。在污染物降解方面，實驗數據顯示經該催化劑催化之Fenton-like具有良好降解苯的能力且可重複催化產生作用。Fe（III）與有機酸複合可以有效提高接觸土壤後水相中Fe（III）的剩餘量，且隨著有機酸莫耳濃度提高水中Fe（III）剩餘量也隨之提高。此外酸性pH之複合鐵接觸土壤會因土壤pH緩衝能力導致水相中Fe（III）剩餘量較少於中性之複合鐵，因此中性複合鐵之有機酸與Fe（III）結合力較強於酸性複合鐵。Fe（III）/有機酸以莫耳濃度為1：1時複合，以一階反應降解苯而反應速率常數與苯之初始濃度成直線關係，當莫耳濃度複合比改變為1：2、1：5、1：10時，其降解苯的反應動力也為一階但反應速率常數卻與苯的初始濃度成非直線關係。現地化學氧化，類Fenton法，複合鐵，苯，反應動力pollutants from the leaking pipeline and storage tanks of petrochemicals are likely to cause soil and aquifer contaminations. The chemical oxidation is successful in remediating soil and aquifer contamination. The mixture of Fe（II） and H2O2 soluton was called Fenton reagent. The Fe（II） ion can catalyze H2O2 to produce hydroxyl radicals ˙OH . The ˙OH is very powerful in oxidizing organic pollutants, reducing their toxicity or even mineralizing them to H2O and CO2. However, the Fenton reagent has limitations such as it reacts more effectively at pH 2~3 and produces precipitates which will cause clogging. Recently, it was found that other Fe-containing compounds work better than Fe（II） ion in catalyzing H2O2 at neutral pH. The Fenton reaction catalyzed by non-Fe（II） ion was called Fenton-like reaction. There are many new catalysts tested nowadays. This study used batch reaction systems to evaluate an Fe（III）/organic acid complex, developed by a consultant firm, to be used as the catalyst of Fenton-like reaction. Using O2 production and decolorization of methylene blue dye as indices, the results