2015聚合物加工基础-作业.docVIP

复习题 Please list some main polymer processing techniques available today Please expound the effects of injection temperature and holding pressure on the quality of final part based on the Fig. 6.61 in the textbook. 3. short answer questions 1 Please give the physical meanings of following symbols: Tb, Tg, Tm, Tf and Td for a polymer; 2 Provide the relevant test standards used for the measurement of the strength stability under heat of a polymer component. 4 the plasticizing extruder can be divided into ， ， ，T screw, and the screw can be or . 4 the main elements of the plasticizing unit of a injection molding machine include: ， ，， ， . 5 the secondary shaping include ， ， ， ， calendaring line is composed of ， ，， ， . 9 the rotational molding process can be divided into six distinct phases: ， ，， ，?， ， ，， ，?， . 5 分析注射制件的残留应力形成原因 Analyze the reasons for the formed residual stresses in injection molded parts. 1） 温度梯度产生的体积温差应力 对于厚壁制品，由于熔体热导率差，外层接近模具面的熔体已经凝固，模腔熔体芯部熔体还处于熔融状态，内层冷凝时材料不能自由收缩，产生拉伸应力，而壳层处产生压缩应力。 2）分子解取向受到阻滞产生内应力 对非晶聚合物，由于熔体冷却造成在充模和保压过程中形成的取向被冻结，形成取向内应力。对于结晶聚合物，玻璃化温度上时受到应力作用而取向的分子链段要自发回复到卷曲状态，但解取向受到结晶相分子的限位，阻止拉伸分子链返回，形成取向应力。 3）结晶聚合物产生的内应力 结晶高聚物结晶，体积收缩，当这种收缩受到阻碍时产生内应力。此外，由于制品各部位结晶结构和结晶度差异、冷却时收缩不均匀也产生内应力。 借助图9.53说明对聚合物不同温度下的剪切模量的影响。Please illustrate the effects of cross-linking on the shear modulus of a polymer at various temperatures by means the Fig.9.53.in textbook. 7 结合图9.55 试说明填料形状和分布方式对聚合物复合材料拉伸模量的影响。 Please expound the effects of the shape and distribution ways of fillers or reinforcement on the tensile modulus of polymeric composites based on the Fig.9.55 in textbook. 简述注射周期的各个注射工段，那一段时间决定注射周期快慢？ Present the sequence of events during the injection molding cycle and the main event dominating the injection molding cycle.It should be noted that the size of the frozen-in free volume depends on the rate at which a material is cooled; high cooling rates result in a large free volume. In practice this is very important. When the frozen-in free volume is large