磷酸二氢钾结晶特性研究.docVIP

磷酸二氢钾结晶过程特性研究 保英莲，张志强，旷天亮 (青海大学化工学院,青海 西宁 810016) 摘 要：采用梅特勒-托利多在线结晶工作站系统地研究了磷酸二氢钾的溶解度、超溶解度、红外特性以及冷却结晶过程的影响因素。研究结果表明，磷酸二氢钾的介稳区在低温区较宽，高温区较窄，且在40.1℃下具有最宽的介稳区；磷酸二氢钾在红外光谱上具有较好的朗伯-比尔特性，其特征峰波数分布在2152cm-1、1082cm-1；降温速率越大，其介稳区宽度也随之增大；搅拌速率越高，其介稳区宽度反而降低；pH为4.0时，其结晶效果最好，粒度分布也最为均匀，晶体颗粒粒径大；Fe3+的含量增大，将会导致磷酸二氢钾的介稳区变宽，并且其含量越大，颗粒越不均匀，粒度分布较宽，因此应严格控制生产工艺中Fe3+的含量≤0.001%；SO42-含量的增大，会使介稳区变窄，将会导致工业上结晶不易控制，因此也需严格控制生产工艺中SO42-的含量。 关键词：磷酸二氢钾；冷却结晶；梅特勒-托利多结晶工作站 中图分类号 TP126.35　　　　文献标识码 A 　　　　 Study on the characteristics of crystallization process of potassium dihydrogen phosphate Bao Yinglian，Zhang zhiqiang, Kuang Tianliang (School Of Chemical Engineering,Qinghai University, Xining 810016,China) Abstract: The project studyed the solubility of potassium dihydrogen phosphate, super solubility, infrared characteristic and the cooling crystallization process of the influencing factors through the METTLER TOLEDO online crystallization workstation .The results showed that the potassium dihydrogen phosphate metastable zone is in a wide temperature region, high temperature zone is narrow, and in 40.1 degrees it have the width of metastable zone. Potassium dihydrogen phosphate in IR spectra has good beer Lambert characteristic. The characteristic peak wavelength can be distributed in 2152cm-1，1082cm-1.And the cooling rate is higher, the metastable zone width increases.The stirring rate is higher, the metastable zone width decreases. When pH is 4, the crystallization is best, the particle size distribution is the most uniform, crystal particle size is maximum. Increasing Fe3+ content, will lead to KH2PO4 metastable zone width, and increasing Fe3+ content, size the wide distribution is uneven, so we should strictly control the production process of the Fe3+ content less than 0.001%. Increasing SO42- content , will narrow the metastable zone, lead to industrial crystallization that is not easy to control, therefore we need to strictly control the content of SO42- in the production process. Keywords:pot