AuZnOTiO2纳米复合材料制备及其修饰电极在重金属离子检测中的应用资料.doc

Au/ZnO/TiO2纳米复合材料制备及其修饰电极在重金属离子检测中的应用 Au/ZnO/TiO2纳米复合材料制备及其修饰电极在重金属离子检测中的应用 摘要： 本文介绍了空心纳米TiO2/Au修饰电极的制备及其在重金属离子检测中的应用。以过氧化钛配合物 (peroxo-titannium complex,PTC)为前驱体、 聚苯乙烯(polystyrene, PS)球为模板,，在水溶液体系中可直接制备得到纳米 TiO2空心球。以醋酸锌与氢氧化钠氨水反应生成ZnO。 同时将ZnO及TiO2混合溶液滴到金电极表面上，再电沉积Au制成ZnO/TiO2/Au修饰电极，利用此修饰电极作为工作电极，采用三电极体系，对水溶液中Hg2+进行电化学检测。 检测结果实验结果表明，纳米空心二氧化钛颗粒/Au/ZnO修饰修饰电极可很好的检测出溶液中Hg2+含量，最低检测线为1×10-10mol/L,在1×10-10mol/L到1×10-4mol/L浓度范围内，方波伏安法峰高和浓度成良好的线性关系，线性相关系数为0.9754。并且灵敏度高，利用该电极重复测量11次，结果表明峰高强度随实验次数变化不大，变化幅度在5%之内，这说明电极稳定性很好，准确度较高，重复性较好。由实验结果可知该电极对污水中Hg2+含量有无超标的检测很有用处。 关键词：空心球、修饰电极、电化学检测.Hg2+。 Abstract: this paper introduces the preparation of nanometer TiO2 hollow/Au electrode and its application in heavy metal ions detection. With peroxide titanium complexes (peroxo - titannium complex, PTC) as precursor, polystyrene (polystyrene, PS) as a template, and in the aqueous solution system can direct the preparation of nanometer TiO2 hollow ball. React with zinc acetate and sodium hydroxide ammonia to form ZnO. And solutions of ZnO and TiO2 onto the gold electrode surface, then electroplating Au ZnO/TiO2 / Au electrode, using the modified electrode as work electrode, using three electrode system, for electrochemical detection of Hg2 + in aqueous solution. Test results the experimental results show that the hollow nanometer titanium dioxide particles/Au/ZnO modified electrode can be very good detection of Hg2 + in the solution, the minimum test line for 10-10 mol/L, 1 x in 1 mol/L x 10-10 to 1 x 10-4 mol/L concentration range, square wave voltammetry peaks and high concentration as a good linear relationship, the linear correlation coefficient of 0.9754. And high sensitivity, repeated measurement using the electrode 11 times, high strength along with the experiment results show that the peak frequency change is not big, change within 5%, which showed that the electrode is good stability, high accuracy and good repeatability. By the experiment result, the electrode of pb2 + in