低品位铝土矿制备石油压裂支撑剂的研究.doc

低品位铝土矿制备石油压裂支撑剂的研究 许娜1，李永刚1，徐亚飞1，杨妮1，1，李怀仁1，刘运连2 （昆明冶金研究院，云南 昆明 650031，昆明理工大学，云南 昆明650093） 摘 要：石油压裂支撑剂是用于支撑水力裂缝的、具有一定强度的固体颗粒物质，其支撑岩层使裂缝始终保持张开状态的同时也有利于石油由地层流出。本文以云南某地低品位铝土矿为主要原料制备石油压裂支撑剂，考察了原料铁含量、烧结温度、升温速率对支撑剂制品的体积密度和破碎率的影响。结果表明：获得满足石油行业标准的支撑剂制品，其原料中铁含量小于6%。最佳烧结温度范围为1380-1420℃，升温制度为干燥时间2h，升温速率400℃/h（3.5 h），保温时间2 h时最佳。 关键词：石油压裂支撑剂；升温制度；烧结温度；破碎率 Investigation of preparing oil fracturing proppant using low grade bauxite Xu na , Li yonggang, Xu yafei, Yang ni, Li huairen, Liu yunlian (1． Kunming Metallurgical Research Institute，Kunming Yunnan 650031，China; 2． Kunming University of Science and Technology，Kunming Yunnan，650093，China；) Abstract Oil fracturing proppant was used for supporting the bolt during oil drilling process which was solid particle with certain intensity, support rock can make the cracks keeping open from beginning to end, at the same time it has been advantage to letting the oil flowing from stratum. In this paper, by using low grade bauxite which produced in certain area of Yunnan province as raw material prepare, by investigating the iron content of raw materials, sintering temperature, and the influence between Volume density and broken rate from different heating rate. The results show that: only the iron content in raw materials is less than 6% can acquire the oil fracturing proppant which achieve the oil industry standards. And the best sintering temperature is from 1380℃ to 1420℃, heating system for drying time is 2h, heating rate is 400℃/h(3.5h) and the best holding time is 2h. Keywords Oil fracturing proppant, heat system, sintering temperature, broken rate 压裂支撑剂是石油开采过程中用来支撑岩缝且具有一定强度的固体颗粒，它可使液体在岩缝中有较高的流通性，增大油流通道及排油体积，减少阻力，达到增产、增注的目的[]。我国从20世纪80年代中期开始研究开发石油压裂支撑剂，其最核心的性能是支撑压裂形成的裂缝并保持开启状态，使裂缝相比于岩层拥有更大的导流能力[]，进而使油气产物连续产出，油田产量增大[]。但目前，国内应用的支撑剂强度较低，若获得强度较高，可在中深井中的支撑剂产品，原料的来源较为困难，工艺复杂，能耗大，成本高[,]。石油支撑剂主要原料为铝矾土，以铝矾土等原料制备石油压裂支撑剂的研究已有许多[,,]，但报道中所用铝矾土的Al2O3质量分数较高，达60%以上。 云南省有较为丰富的铝土矿资源，根据云南省国土资源厅储备评审中心备案，云南鹤庆地区大黑山、白水塘、松桂、大果和乐五区铝土矿储量为641.06万吨，但矿石中Al2O3质