朱耀武-07401534-石墨烯四氧化三鐵复合材料在处理印染废水中的应用-毕业论文.docVIP

学号： 常 州 大 学 毕业论文 （2011届） 题 目 石墨烯/四氧化三铁复合材料在处理印染废水中的应用 学 生 朱耀武 学 院 石油化工 专 业 班 级 化工075 校内指导教师 何光裕 专业技术职务 副教授 校外指导老师 专业技术职务 二○一一年六月 PAGE III 石墨烯/四氧化三铁复合材料在处理印染废水中的应用 摘要：本文通过简易的共沉淀方法制备了磁性可分离的石墨烯/四氧化三铁纳米复合材料。本文研究了以GE/Fe3O4复合材料作为催化剂，在光照或加热条件下使H2O2分解为氧化性极高的羟基自由基（·OH），催化降解酸性红RS。本文比较了GE、Fe3O4、及GE/Fe3O4催化脱色试验，GE/Fe3O4的吸附实验和非催化氧化实验的效率，讨论了不同的pH、温度和不同条件（加热、超声和光照）下反应时间对染料溶液脱色效果的影响。实验结果表明，非催化反应效率低下，吸附脱色水平较低，GE、Fe3O4单独使用时催化效果低微，然而GE/Fe3O4复合材料确显示了非凡的催化效果，即在H2O2存在条件下，GE与Fe3O4协同促进大大提高了酸性红RS的降解效果。 关键词：磁性、纳米复合物、催化降解、石墨烯/四氧化三铁 The application of graphene / Fe3O4 composite materials in dyeing wastewater Abstract: A magnetically separable graphene/Fe3O4 nanocomposite catalyst was prepared by a facile co-precipitation method. The acid red RS catalytic degradation reaction was conducted under ultrasonic, irradiant or heat conditions HYPERLINK /with/ \t _blank with graphene/Fe3O4 nanocomposite as the HYPERLINK /catalyst/ \t _blank catalyst, and the effect was discussed of different reaction pH, temperature and the time under HYPERLINK /different/ \t _blank different conditions, such as heat, ultrasound and irradiant. In comparison with the efficiency of photocatalytic decolorization test with graphene, Fe3O4 and graphene/Fe3O4, adsorption experiments with graphene/Fe3O4 and non-catalytic oxidation experiments. The results showed that non-catalytic reaction and absorption bleaching is inefficient, and the effect of using graphene or Fe3O4 alone was low. However, the catalytic effect of graphene/Fe3O4 composites was remarkable, because graphene/Fe3O4 serves a dual function as the catalyst for photoelectrochemical degradation of acid red RS and the generator of a strong oxidant hydroxyl radical (·OH) via photoelectrochemical decomposition of H2O2 under visible light irradiation. Key words: Magnetic, Nanocomposite, Catal