甲醇催化羰基化制乙酸工藝的发展.docVIP

甲醇催化羰基化制乙酸工艺的发展 赵文国 Advances in the Industrial Production of Acetic Acid via Carbonylation of Methanol 摘要： 甲醇催化羰基化是目前世界上工业生产乙酸最主要的方法，用这一工艺生产的乙酸占世界乙酸总产量的60 %以上。目前甲醇羰基化法主要工艺有BASF工艺、Celanese公司改进的Monsanto工艺和BP公司的CativaTM工艺。然而，这些工艺还都有各自的不足，仍有待改进。 关键词：甲醇，乙酸，羰基化，催化 Abstract: Catalyzed carbonylation of methanol is the most significant method for the production of acetic acid. More than 60 % of the global acetic acid is produced via this method. Nowadays, methanol carbonylation methods used in the industrial production of acetic acid include BASF method, advanced Monsanto-method by Celanese and Cativ