石墨烯自组装.pptVIP

Company Logo LOGO Company Logo * Understanding the Formation Mechanism of Graphene Frameworks Synthesized by Solvothermal and Rapid Pyrolytic Processes Based on an Alcohol-Sodium Hydroxide System 学生：刘志 学号 汇报内容 第一部分：石墨烯的应用及难题 第二部分：石墨烯制备步骤 第三部分：机理分析 第四部分：合成方法比较 石墨烯的应用及难题 石墨烯产量低生产条件苛刻限制了大规模合成和应用 解析其合成机理有利于石墨烯的大规模、低成本、可控的合成和制备 石墨烯的制备 3.5g NaOH+8ml n-propanol 200℃ 36h solid solvothermal product rate of 10℃/min for 100min transfer to combustion boat decompose at 60℃/s for 60s Ar stream cool to RT wash several times with deionized water filtered overdried 60℃ 24h vocuum sample PS:碳源是其他醇，过程完全相同。是乙酸时，溶剂热反应温度为180℃，裂解温度为1150℃ 实验分析 Characterization of GFs synthesized from n-propanol and sodium hydroxide . Pure 3D networks constructed with graphene sheets 实验分析 AFM image of GFs.The thickness is about 3 nm for few-layer graphene. The Raman spectrum is shown in Figure 1d, and the G-band at 1586 cm?1 demonstrates the formation of graphitic carbon. 实验分析 Excluding n-propanol, other alcohols (such as methanol,ethanol, and butanediol) can also be used to produce graphene. That suggests a generality of the method of graphene synthesis: Sodium hydroxide was used instead of sodium, the development process became much safer and easier. SEM images of GFs synthesis based on different alcohol sources and sodium hydroxide: (a) methanol, (b) ethanol, and (c) 1,4-butanediol. 实验分析 Alcohol and sodium hydroxide can react to form sodium alcoholate sodium alcoholate instead of alcohol + sodium hydroxide ??? 实验分析 sodium alcoholate can not instead of alcohol + sodium hydroxide 实验分析 Pore size distribution of solvothermal product of n-propanol and sodium hydroxide The solvothermal product had two obvious pore distributions at 10~100 nm and 3~4 nm. 实验分析 TGA-MS analysis of the solvothermal product: (a, b) n-propanol and sodium hydroxide; (c, d) ethanol and sodium hydroxide. 小结 A precursor of the porous structure of sodium alcoholate and