《普鲁士蓝薄膜的电沉积及其电致变色性能毕业论文》.docVIP

本科毕业论文普鲁士蓝 所在院系：城市建设与环境工程学院学生姓名：曹哲超 班级名称：10化学A1 学 号：10 专业名称：材料化学（绿色电子材料） 指导教师：王金敏 二○一四年五月Shanghai Second Polytechnic University (SSPU)School/Department: School of Urban Development and Environmental Engineering Student Name: Zhechao Cao Class: 10 Chemical Class A1 Number：10 Major: Materials Chemistry Teacher: Jinmin WangMay, 2014 摘要 普鲁士蓝及其衍生物材料在催化、光学、电磁学、热学、电子学、传感器、力学等方面都表现出不同于传统材料的优异特性，它引起了科学工作者的广泛关注。如能实现对纳米材料颗粒大小、形貌及晶化度等特性的控制合成，必将给这一古老而重要的材料带来一次新的发展生机关键词：普鲁士蓝；电致变色Abstract Prussian blue and its derivatives materials in catalysis, optics, electromagnetism, thermology, electronics, sensors, mechanical showed excellent properties of different from traditional materials, it caused the? wide attention of scientific workers . If you can realize the nano material particle size, morphology and crystallization degree of features such as control, will certainly give this ancient and important material to bring a new vitality for development. In the hydrothermal reaction, structure and morphology of the synthesized under different reaction conditions Prussian Blue nanocrystalline particles are not the same. Comparing by characterizing Prussian Blue nannoparticles, we know when pH=1, PVP=3g, K3Fe(CN)6=0.1mol/L, the synthesis of Prussian blue nanocrystalline particles surface are smooth, the size of the particles of Prussian Blue nanocrystals between 300-500 nanometers. The synthesis of Prussian blue nanoparticles made ??of Prussian blue film on conductive glass, compare their electrochemical performance analysis by electrochemical workstation. Key Words: Prussian blue; Film; Electrochromism 目录 Abstract Ⅱ 目录 Ⅲ 第一章 绪论 1 1.1概述 1 1.2电致变色 1 1.2.1电致变色的定义 1 1.2.2电致变色材料 2 1.2.3电致变色的现象 3 1.2.4电致变色器件的应用 4 1.2.4.1电致变色显示 4 1.2.4.2电致变色智能窗 4 1.2.4.3防眩后视镜 5 1.2.5 普鲁士蓝电致变色 5 1.3 普鲁士蓝的性质及应用 5 1.4 普鲁士蓝的结构特征 6 1.5 普鲁士蓝的制备方法 7 1.5.1水热法 7 1.5.1.1水热条件下的特性 8 1.5.1.2水热合成普鲁士蓝 8 1.5.2电化学沉积法 8 1.5.3连续离子吸附法 9 1.5.4反向微乳胶法 9 1.6 普鲁士蓝薄膜 9 1.6.1 普鲁士蓝薄膜的制备 10 1.6.2 普鲁士蓝膜的电化学活性 10 1.6.3 普