本科毕业设计---光催化.docVIP

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  • 2016-12-13 发布于辽宁
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摘要:窗体顶端 摘要:半导体光催化材料在太阳能利用和氧化降解污染物方面的广泛应用。作为一般的光催化材料,TiO2具有相对高的活性,稳定性和耐化学性。然而,TiO2只能响应占用可见光很少的光紫外线,产生的电子 - 空穴的分离效率不高。为了解决这些问题,具有可见光响应的材料制成的新的光催化的开发势在必行。 BiOI作为一种新的光催化剂,由于其特殊的层状结构表现出相对优异的可见光利用率,从而提高对有机污染物光催化降解性能。已经制备的异质结构已被证明是一种有利于电子 - 空穴的分离的结构,从而能够显著提高光催化性能BiOI。 此次研究以冰乙酸、碘化钾、碘酸钾、硝酸铋为原料,BiOIO3 是经过简单的水热法制得的。而BiOIO3/BiOI是通过化学沉淀法制得的。采用XRD、SEM、TEM、BET比表面积、XPS、UV-vis DRS、PL、ns-level TRF spectra等对BiOIO3/BiOI 异质结进行表征,结果表明异质结构的制备是一种非常有利于光生电子空穴分离的方法,并且可显著提高 BiOI 对NOx的光催化性能。故这种异质结构在未来有广阔的应用前景。 关键词:BiOI 异质结 光催化NOx Abstract:窗体顶端 、Semiconductor photocatalytic oxidation in the utilization of solar energy and Degradation of great application. As one of ordinary photocatalytic material advantages of TiO 2 having a relatively high activity, good stability and chemical resistance. However, it is only in response to ultraviolet light, which accounts for a small portion of sunlight. Besiedes, titanium dioxide electron - hole separation efficiency is quite slow. Because of these factors, the development of photocatalytic material who has the ability to respond to visible light is necessary. As one of the new photocatalysts, BiOI exhibit photocatalytic degradation of organic pollutants more superior performance. The reason for this is its high-performance special layered structure. Constructed heterostructure has proven to be quite useful way to separate photo-generated electrons - hole, to further improve the photocatalytic properties.窗体底端 Abstract:Semiconductor photocatalytic oxidation in the utilization of solar energy and Degradation of great application. As one of ordinary photocatalytic material advantages of TiO 2 having a relatively high activity, good stability and chemical resistance. However, it is only in response to ultraviolet light, which accounts for a small portion of sunlight. Besiedes, titanium dioxide electron - hole separation efficiency is quite slow. Because of these factors, the development of photocatalytic material who has the ability to respond to visibl

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