涂层用硬质金基体表面预处理方法综述.docVIP

2012届本科毕业论文（设计） 论文题目：涂层用硬质合金基体表面预处理方法综述 学生姓名： 所在院系： 机电学院 所学专业：机械设计制造及其自动化 导师姓名： 完成时间：2012年5月18日 摘 要 本文分析和综述了影响金刚石涂层硬质合金基体粘结性的主要因素。按照其原理来分，预处理方法可分为物理预处理法、化学预处理法以及中间层法。通过适当的预处理能有效消除或抑制基体中钴粘结相的负面影响，提高金刚石涂层与硬质合金基体间的粘结强度。全面概述了金刚石涂层硬质合金刀具的开发现状、存在的主要问题，重点对硬质合金刀具表面预处理方法的研究现状进行了综述，发现甲醇预处理方法对硬质合金衬底表面抑制Co催石墨化作用。将甲醇预处理方法融入到传统的两步处理方法中,提出了新的两步预处理方法,采用甲醇预处理方法能够有效抑制Co对金刚石薄膜的不利影响,新的两步预处理方法既能保证金刚石薄膜与衬底之间的附着强度,又非常适用于复杂形状整体式回转硬质合金刀具、拉拔模具等衬底,对于拓展金刚石涂层在涂层刀具领域的应用具有一定的参考作用。 关键词：金刚石涂层；硬质合金；表面预处理 Abstract In this paper，mainly analysis and summarizes the main factors of impacting the adhesion between diamond coatings and carbide substrate．According to the principle the surface pretreatment method can be divided into physical pretreatment method，chemical pretreatment method，and the middle layer method．Through the appropriate pretreatment can eliminate or inhibit the negative impact of cobalt binder phase in the substrate and increase the strength between the diamond coating and the cemented carbide substrate．Comprehensive overview of diamond coated cemented carbide cutting tools development present situation, the existing problems, emphasis on cemented carbide cutting tools surface pretreatment method research are reviewed.A methanol pretreating method was proposed to reduce the Co concentration on the surface of WC-Co substrate; also a new two-step chemical procedure The results showed that the new two-step method increases the diamond nucleation density and enhance the adhesion strength greatly. The new two-step chemical procedure is very suitable for complex shaped substrates, such as rotational cutting tools and drawing dies, which may broaden the use of diamond coatings for coated tool applications. Key Words：Diamond coatings；Cemented carbide；Surface pretreatment  目 录 1绪论 1 1.2国内外研究现状 1 1.2.1 高速切削的优越性 1 1.2.2 硬质合金刀具材料的应用 1 1.3刀具切削加工技术的重要发展趋势 2 2设计要求 2 3影响涂层与基体粘结性的不利因素 3 4基体表面预处理方法 3 4.1基体表面机械处理 3 4.2化学浸蚀液（酸洗）清洗法 4 4.3硬质合金表面激光辐照（热）处理 5 4.4添加粘结促进剂 5 4.5氧化处