PET耐磨抗划伤涂层的制备.docVIP

本科学生毕业论文 PET耐磨抗划伤涂层的制备 全国话费充值 全国各种产品批发 指导教师： 全国最质优价廉 职 称： 5分/面 全国网络批发商城 T The Graduation Design for Bachelors Degree Preparation of Wear-resistance and Scratch-resistance Coating Applied on PET Candidate：Harbin 摘要 高分子材料性能优异，但也有质软，不耐磨的缺点，这大大限制了应用范围。对材料进行改性处理是提高材料耐磨性能和抗划伤性能的有效方法在很多情况下，对一廉价的材料，应用表面涂层技术能极大地改善材料的性能，达到最佳性价比本文将对PET薄膜表面耐磨抗划伤涂层进行研究，探讨其配方、制备工艺和耐磨抗划伤性能，并总结提出一个基本的配方和制作工艺。 实验中采用KH56熟化，涂覆在PET薄膜上，在一定的温度，固化剂作用下固化得到耐磨抗划伤涂层。 实验测试比较了KH560和TEOS不同比例下，以及添加不同含量二氧化硅对涂层的铅笔硬度、耐磨性能、抗划伤性能的影响。利用TG对水解熟化后的产物进行分析，探讨固化过程及机理。利用红外光谱测试探讨水解过程及固化产物的结构。 实验结果初步得到涂层的配方和制备工艺，测试显示涂有保护涂层的PET薄膜的硬度、耐磨性以及抗划伤有很大的提高，并对涂层的结构进行了初步的研究。 关键词涂层；铅笔硬度；耐磨抗划伤 ABSTRACT As we know that the polymer materials have the high performance in common applications. However, its softness and weak wear resistance, which greatly limit its further application. Modification on polymeric materials is an effective way to improve the wear-resistance and scratch-resistance. In many cases, the performances of the low cost materials can be improved greatly by the surface coating technology, which can effectively improve the material performance. In this paper, this study tried to improve the wear resistance of silicone scratch coating at BOPET film surface by the surface coating method. The process to prepare the coating and the optimal composition would be studied. At last, a basic formula and the production process would be proposed. In the experimental I use the catalytic hydrolysis product of KH-560 as the main raw material, and the SiO2 hydrolyzed by TEOS with the existing nano-silica powder as filler. The three parts mixed and then to be smeared on the PET film, with an appropriate at a certain temperature curing agent. And then the anti-scratch and wear-resistant coating is made. The influence on the pencil hardness, wear resistance, anti-scratch properties are compared under the different proportion of KH-560 and TEOS and the different content of nano-silica pow