工程环境保护与可持续发展_第4章__大气污染的控制与治理.ppt

Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * Academic Seminar * 3. 烟气脱硫FGD (Flue Gas Desulfurization) 技术成熟，大规模应用。100多种，实用十几种。 难点：烟气量大、SO2浓度低，初投资及运行费用高，目前基本上只应用于电站。 技术基础：用金属氧化物和活性炭吸附SO2，或用碱性溶液吸收SO2。 有两类方法： 干法：固态脱硫剂，气固反应慢，η较低，但脱硫产物易处理，投资低于湿法，有利于烟气排放。 湿法：溶液吸收，η高，技术成熟，但脱硫产物难处理，投资较大，烟温降低不利于排放。 半干法：脱硫剂是液态，脱硫产物是固态。 抛弃法：S02转化为固体产物后,以抛弃为主； 回收法：制取硫酸、硫磺、石膏等有用物质。 （1） 干法烟气脱硫 ①电子束法 原理：电子加速器产生的等离子体（烟气中O2、H2O+能量→活性O、OH ，氧化性物质O3、HO2 ）氧化SO2（NOx），并与NH3反应，生成S铵和N铵（气溶胶微粒带有电荷，易捕集。）化肥。 1970年日本荏原(Ebara)公司首先提出。示范厂取得预期效果，1998成都电厂90MW机组上实施。 特点：η≥90％，同时脱硫脱硝，投资低，产物作肥料，无废渣，但运行电耗高，受肥料