偏三甲苯甲醇烷基化制备均四甲苯的..docVIP

偏三甲苯甲醇烷基化制备均四甲苯的研究 摘要： 对偏三甲苯与甲醇的反应进行了热力学分析，计算了不同温度下的反应焓变和平衡常数；进行了气相色谱柱的筛选和均四甲苯在偏三甲苯中的溶解度测定；在管式反应器内进行了空白实验和催化剂的活性实验。实验结果表明偏三甲苯的转化率大于24%，均四甲苯的选择性大于97.2%。 关键词：均四甲苯，偏三甲苯，烷基化 ALKYLATION OF 1，2，4-TRIMETHYLBENZENE WITH METHANOL TO FORM 1，2，4，5-TETRAMETHYLBENZENE Abstract： Tof 1,2,4-Trimethylbenzene with methanol on HZSM-5 zeolite catalysts was studied. the enthalpy of reaction and equilibrium-constant under different temperature were calculated. gas phase column was choosed and the solubility of 1,2,4,5-Tetramethylbenzene in 1,2,4-Trimethylbenzene was measured. In the pipeline reactor, t