联j想的激励政策.docxVIP

摘 要ASA树脂是由苯乙烯、丙烯腈、丙烯酸丁酯三元聚合物共聚合成的一种改性树脂，具有良好机械物理性能、很强的耐候性、较好的耐高温、防静电等特点。其中，在合成ASA树脂过程中，接枝交联丙烯酸酯的接枝度对ASA树脂的综合性能有着重要的影响。本文以“橡胶胶乳的合成→扩径→接枝→凝聚→洗涤→干燥”为合成工艺路线进行了接枝交联丙烯酸酯的反应，探讨了乳化剂用量、引发剂用量对接枝率的影响。运用粒度分析仪，红外光谱对接枝交联丙烯酸酯进行了粒径大小及其结构的表征。结果表明，在本实验条件下，合成出了接枝交联丙烯酸酯聚合物；接枝聚合物的接枝率和接枝效率随乳化剂用量增大而增大，但当增加到极大值，且乳化剂用量为0.5%左右，接枝率和接枝效率又开始缓慢减小；另外，接枝交联丙烯酸酯聚合物接枝率和接枝效率也随引发剂用量增大而增大。关键词：橡胶胶乳,ASA树脂,接枝共聚,红外吸收光谱ABSTRACTASA resin is synthesized from styrene, acrylonitrile, butyl acrylate terpolymer copolymer modified resin with good mechanical and physical properties, strong weather resistance, high temperature, anti-static characteristics. In the process of synthesis ASA resin, grafted crosslinked acrylate graft degree of the integrated performance of the ASA resin has an important influence.In this thesis, the graft crosslinking acrylate reaction for the synthesis of process routes is “Synthetic rubber latex → expanding → grafting → cohesion → washing → drying”.The amount of emulsifier, the amount of crosslinking agent on the grafting yield. The particle size analyzer, infrared spectroscopy to the characterization of particle size and structure of the graft crosslinked acrylate.Under our experimental conditions, the results show that the synthesis of graft cross-linked acrylic polymer; graft polymer grafting ratio and grafting efficiency increases with the amount of emulsifier, but when added to a great value, and the amount of emulsifier is about 0.5%, the grafting percentage and grafting efficiency decreases slowly; In addition, the graft cross-linked acrylic acid ester polymer grafting ratio and grafting efficiency also increases with the amount of initiator increases.KEY WORDS：Rubber latex, ASA resin, graft copolymerization, IR目 录file:///C:\Users\lenovo\Desktop\郭轩毕业论文.doc前 言1file:///C:\Users\lenovo\Desktop\郭轩毕业论文.doc第1章 文献综述2file:///C:\Users\lenovo\Desktop\郭轩毕业论文.doc1.1 ASA树脂简介2file:///C:\Users\lenovo\Desktop\郭轩毕业论文.doc1.1.1 ASA树脂的结构与性能3file:///C:\Users\lenovo\Desktop\郭轩毕业论文.doc1.1.2 ASA树脂的耐热性3f