b原子能级..docVIP

原子轨道能级表* （原子单位，表中是绝对值，实际原子轨道能级是相应的负值） He 2 Li 3 Be 4 B 5 C 6 N 7 O 8 F 9 1s2 1s22s1 1s22s2 1s22s22p1 1s22s22p2 1s22s22p3 1s22s22p4 1s22s22p5 1s 0.861 2.199 4.349 7.187 10.689 14.869 19.728 25.269 2s 0.202 0.301 0.462 0.645 0.848 1.072 1.317 2p 0.250 0.330 0.422 0.520 0.625 Ne 10 Na 11 Mg 12 Al 13 Si 14 P 15 S 16 1s22s22p6 [Ne]3s1 [Ne]3s2 [Ne]3s23p1 [Ne]3s23p2 [Ne]3s23p3 [Ne]3s23p4 1s 31.50 39.03 47.50 56.83 67.02 73.06 84.99 2s 1.584 2.362 3.276 4.356 5.544 6.842 8.255 2p 0.736 1.335 2.072 2.974 3.977 5.090 6.314 3s 0.189 0.253 0.372 0.498 0.629 0.765 3p 0.179 0.240 0.302 0.378 Cl 17 Ar 18 K 19 Ca 20 Sc 21 Ti 22 V 23 [Ne]3s23p5 [Ne]3s23p6 [Ar]4s1 [Ar]4s2 [Ar]3d14s2 [Ar]3d24s2 [Ar]3d34s2 1s 102.68 126.74 131.05 146.65 163.15 180.39 198.48 2s 9.785 11.433 13.530 15.813 17.987 20.261 22.645 2p 7.652 9.104 11.004 13.090 15.065 17.289 19.323 3s 0.906 1.553 1.476 1.938 2.215 2.491 2.769 3p 0.453 0.537 0.866 1.241 1.442 1.638 1.835 3d 0.265 0.314 0.359 4s 0.153 0.199 0.215 0.229 0.241 Cr 24 Mn 25 Fe 26 Co 27 Ni 28 Cu 29 [Ar]3d54s1 [Ar]3d54s2 [Ar]3d64s2 [Ar]3d74s2 [Ar]3d84s2 [Ar]3d104s1 1s 217.23 237.24 257.91 279.40 301.85 324.85 2s 25.645 27.755 30.478 33.324 36.280 39.070 2p 21.390 24.025 26.542 29.179 31.930 34.510 3s 2.856 3.340 3.635 3.939 4.250 4.317 3p 1.846 2.239 2.446 2.620 2.878 2.855 3d 0.239 0.443 0.481 0.521 0.558 0.372 4s 0.215 0.262 0.272 0.282 0.292 0.255 ___________________________ *Herman, F., Skillman, S., Atomic structure calculations, Prentice-Hall, Inc. Englewood Cliffs, N. J. 1963 Zn 30 Ga 31 Ge 32 As 33 Se 34 Br 35 [Ar]3d104s2 [Ar]3d104s 4p1 [Ar]3d104s24p2 [Ar]3d104s24p3 [Ar]3d104s24p4 [Ar]3d104s24p5 1s 349.2 374.6 400.9 428.2 456.3 485.4 2s 42.56 46.32 50.26 54.37 58.65 63.12 2p 37.78 41.31 45.03 48.91 52.98 57.22 3s 4.897 5.619 6.381 7.188 8.037 8.928 3p 3.331 3.946 4.598 5.294 6.029 6.806 3d 0.629 1.020 1.445 1.911 2.417 2.962 4s 0