微波水热法制备KEu(MoO4)2红色荧光粉简析.doc

毕业论文 课题名称 微波水热法制备KEu(MoO4)2红色荧光粉 院 (系) 材料科学与工程学院 专 业 复合材料与工程 姓 名 周峥 学 号 1105110130 起讫日期 2015.1-2015.6 指导教师 刘云飞 2015年 06月03日摘 要 白色发光二极管因为具有低能耗、轻便、发光颜色丰富、发光性能优良、响应迅速等优点，在照明领域得到广泛使用。白光 LED 发展到如今，效率最高的实现方式用紫外光 LED 激发芯片，发出紫外光从而可以激发红蓝绿混合荧光粉白光，但发展的瓶颈是缺少高发光寿命长的红色荧光粉。Eu3+ 作为LED研究领域的稀土荧光材料，由于 Eu3+ 的 5D0→7F2 跃迁，经过紫外光照射后红色区域会发出纯正的强光，因此在制造红色荧光粉中被使用。钼酸盐因为稳定的化学性质和良好的物理性能，被大量用作荧光基质材料。 目前荧光粉的生产方式大多为高温固相反应法，存在产物不均匀、发光效率低、能耗大等缺点。微波水热法是一种新颖的反应方法，，。由于使用热液反应方式，产物形貌规整，大小均匀。因此，本文采用微波水热法，KEu(MoO4)2 粉体。通过研究不同参数对合成 KEu(MoO4)2 的影响，良好的产物并进行表。 关键词：白光 LED KEu(MoO4)2 微波水热法 ABSTRACT White light-emitting diode as a low power, lightweight, rich luminous color, light performance, quick response, are widely used in the lighting field. White LED development to the present, the most efficient way to achieve that is to use ultraviolet LED chip as the excitation and emit ultraviolet light which can excite red, blue and green mixed phosphors to get white light. However, the current development bottleneck is the lack of high luminous efficiency, long life of red light-emitting phosphor. Eu3+ as the rare earth fluorescent materials, has extensive research in the field of LED in recent years. because of the Eu3+ 5D0 → 7F2 transition, after UV irradiation, the red zone will be issued color pure light, so the manufacture of red phosphors are widely used . Molybdate as stable chemical properties and good physical properties, it is widely used as a fluorescent host material. Currently phosphor production mostly high temperature solid state reaction method, there is a product of uniform, low luminous efficiency, energy consumption and other shortcomings. Microwave hydrothermal method is a novel reaction method, the heating is fast and uniform, the intense collision of the water molecule and the reaction generates creates lots of heat. The reaction is fast and uniform and has the large development space. Due to the use of hydrothermal reaction, the morphologies hanv a un