《12-03-22高三化学理综试卷3讲评课件.pptVIP

湖南长郡卫星远程学校 2012年上学期 制作 12 理综试卷3讲评 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 7 D 8 B 9 D 10 C 11 D 12 D 13 C Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 26. (14分) (1)①②④⑨(2分) Al2S3(2分) (2)1∶2(2分) (3)Al3＋ + 3AlO2－ + 6H2O = 4Al(OH)3↓(3分) (4)Na2S2O3 + H2SO4 = Na2SO4 + SO2↑ + S↓ + H2O(3分) (5)前者大 (2分) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 27. (14分) (1)A (2分) (2)2H+ + 2e- ＝ H2↑ (或2H2O + 2e- ＝H2↑+ 2OH-)(2分) (3)从右向左(2分) 　滤纸上有红褐色斑点产生(答出“红褐色　斑点”或“红褐色沉淀”即可给分)(2分) (4)增大 (2分) (5)0.28 (2分) (6)2FeO42- +6e- +5H2O＝Fe2O3+10OH- (2分) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 28. (15分) (2)B(2分)MnO2+4H++2Cl- ===Mn2++Cl2↑+2H2O(2分) (3)同素异形体(1分)固态的结构不同，液态时结构相同(2分) (4)c→f, g→h, i→d, e→a, b→h (2分) (5)设计中缺吸收尾气的装置与药品，在导管b后添加一个装有碱石灰干燥管。或在i后接一个盛装NaOH水溶液的尾气吸收装置(2分) 图略(2分) △ Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 36. (15分)化学选修—化学与技术 (1)氧化—还原法(2分) (2)CN-+ClO-===CNO-+Cl-(3分) (3)调节废水pH，使其转化成Cr(OH)3沉淀除去 (4分，其他合理答案也给分) (4)3S2O32-+4Cr2O72-+26H+ ===6SO42-+8Cr3+ +13H2O(3分) (5)Cu2++2OH- === Cu(OH)2↓ 　Cu(OH)2(s)+S2-(aq) === CuS(s)↓+2OH-(aq) 　或Ksp(CuS)Ksp[Cu(OH)2],使沉淀向 更难溶方向转化。(3分) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 37. (15分)化学选修—物质结构与性质 (1)1S22S22P63S23P63d24S2(2分) (2)BaTiO3(2分) (3)面心(2分) (4)6 呈正八面体分布(每空3分，共6分) (5)61. 5pm(3分) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 38. (1) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd.