[化工热力学总结2.pptVIP

解得： = 66℃ ⑴ 熵分析： 因是绝热过程，所以Q=0， ，故过程熵产为： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 由附表3可查得： 所以： 火用损失即为功损耗，即 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. （2） 火用分析法 从附表3分别查得各状态下水的焓和熵值为 温度（℃） 90 50 66 25 熵（ ） 1.1925 0.7038 0.9059 0.3674 焓（ ） 376.92 209.33 276.36 104.89 ， Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 90℃时水的物理火用为： 50℃时水的物理火用为： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 66℃时水的物理火用为： 所以： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 第七章重点内容 化学位的表达式： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 两个重要的方程式 ： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 偏摩尔性质 偏摩尔性质与溶液摩尔性质间的关系 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 偏摩尔性质的计算： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. （T 恒定） 纯物质 i （T 恒定） 混合物整体 （T 恒定） 混合物中的 i 组分 逸度的定义 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 是 的偏摩尔性质 §：根据摩尔性质与偏摩尔性质的关系 可得： Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 纯物质 混合物组分 7.2.4 T、p对逸度的影响 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile 5.2.0.0. Copyright 2004-2011 Aspose Pty Ltd. 稀溶液的溶质近似遵守亨利定律。 普遍地表现出能符合理想混合物规律的有两个浓度区： xi 1 xi 0 亨利定律 L-R规则 因此，一个更为广义的理想混合物的定义式应为 标准态逸度 理想混合 Evaluation only. Created with Aspo