小粒径聚合物暂堵剂.doc

毕业设计（论文） 小粒径聚合物暂堵剂 学 生 姓 名 王湉 学 号 专 业 班 级 高分子材料科学与工程 指 导 教 师 张定军 副教授 提 交 日 期 材料科学与工程学院 摘 要 蒙脱土与聚丙烯酰胺形成纳米复合体系的研究引起了人们的极大关注。PAM 类聚合物/黏土纳米复合材料是把纳米尺寸的黏土片层分散在PAM 聚合物基体中形成的复合材料。它吸水能力大,保水性好,凝胶强度高,不仅具有纳米材料的表面效应、量子尺寸效应等性质,而且将黏土的刚性、尺寸稳定性和热稳定性与PAM 聚合物的韧性、加工性及介电性能揉合在一起,从而明显改善了PAM 类高分子材料的物理机械性能、热稳定性、气体阻隔性和光学等性能, 提高了耐温、抗剪切、抗污染等综合性能,能更好地应用于石油钻采等领域。关于采用聚丙烯酰胺类聚合物/蒙脱土纳米复合材料制备暂堵剂,本文采用原位插层聚合法制备了聚丙烯酰胺/蒙脱土纳米复合材料类暂堵剂，并对制备工艺条件进行了优化。着重探讨了单体配比、中和度、蒙脱土含量、引发剂量等对复合材料性能的影响。 丙烯酰胺丙烯酸蒙脱土复合材料水溶性高分子ABSTRACT Montmorillonite nanocomposites has aroused great concern to the formation of polyacrylamide. The PAM polymer / clay nanocomposites is the nano-size clay layers dispersed in the PAM polymer matrix composites. It absorbent capacity, water retention, gel strength, not only has the surface effect of nano-materials, the nature of the quantum size effect, etc. and the rigidity of the clay, dimensional stability and thermal stability of PAM polymer toughness, workability and dielectric properties of blend together, which significantly improved the physical and mechanical properties of the PAM class of polymer materials, thermal stability, gas barrier and optical properties, improved heat resistance, shear, anti-pollution and other performance can be better used in oil drilling and other fields. Temporary blocking agent, on the use of polyacrylamide polymer / montmorillonite nano-composites using in situ intercalative polymerization preparation of PAM / MMT nanocomposites class temporary blocking agent, and the preparation conditions were optimized. Focused on the influence of the monomer ratio, and the degree of MMT content, initiator, solvent volume on the solubility of the composite. KEYWORDS:acrylamide,acrylicacid,montmorillonite,composites,water-soluble polymer 第一章