大学生本科毕业设计模板(实验类)..docVIP

摘 要 本论文采用在线测氧法对系列1.0G树枝状受阻酚类抗氧剂和系列1.0超支化大分子受阻酚类抗氧剂清除ROO·的能力进行了研究，考察了酚羟基浓度及桥联基长度对抗氧剂清除自由基能力的影响。结果表明，随酚羟基浓度的增加，系列受阻酚类抗氧剂的抗氧化能力增强。在反应条件相同时，系列树状桥联受阻酚类抗氧剂的抗氧化能力大小顺序为：乙二胺为核1.0G树枝状受阻酚抗氧剂丁二胺为核1.0G树枝状受阻酚抗氧剂己二胺为核1.0G树枝状受阻酚抗氧剂辛二胺为核1.0G树枝状受阻酚抗氧剂;系列超支化受阻酚类抗氧剂清除自由基能力的大小顺序为：十八胺为核1.0G超支化受阻酚抗氧剂十六胺为核1.0G超支化受阻酚抗氧剂十四胺为核1.0G树枝状受阻酚抗氧剂十二胺为核1.0G超支化受阻酚抗氧剂。 关键词：树枝状受阻酚类抗氧剂；超支化受阻酚类抗氧剂；测氧法；酚羟基浓度；抗氧化性能 Abstract The ability of removing ROO· of series 1.0G dendritic hindered phenolic antioxidants and series 1.0 hyperbranched macromolecules hindered phenolic antioxidants were studied by oxygen uptake measurement in this paper. The effects of the concentration and the length of the bridged group of antioxidant phenolic hydroxyl on the abilities of scavenging ROO·were also studied. The results showed that antioxidant abilities increased with the increase of concentration of antioxidant phenolic hydroxyl. Under the same conditions, the order of the antioxidant abilities of dendritic antioxidant was 1.0 generation of ethylenediamine antioxidant, 1.0 generation of butylenediamine antioxidant, 1.0 generation of hexanediamine antioxidant, 1.0 generation of octanediamine antioxidant, and the order of the antioxidant abilities of hyperbranched antioxidant the abilities of removing ROO· was 1.0 generation of octadecylamine antioxidant, 1.0 generation of hexadecylamine antioxidant, 1.0 generation of tetradecylamine antioxidant and 1.0 generation of dodecylamine antioxidant. Key words: 1.0G dendritic hindered phenolic antioxidants; 1.0G hyperbranched hindered phenolic antioxidants; oximetry; phenolic hydroxyl concentration; antioxidant properties  目 录 第1章 概述 1 1.1 高分子材料的热氧化机理 1 1.2 酚类抗氧剂的结构与性能 2 1.3 酚类抗氧剂抗氧化性能的评价方法 4 1.4 受阻酚类抗氧剂的应用和发展前景 8 1.5 本课题的目的与意义 9 第2章 实验部分 12 2.1 实验药品及仪器 12 2.2 系列受阻酚类抗氧剂的合成 13 2.3 测氧法的实验原理 14 2.4 在线测氧法的实验步骤 16 第3章 结果与讨论 17 3.1 系列受阻酚类抗氧剂的分子结构分析 17 3.2 系列1.0G树枝状受阻酚抗氧剂的抗氧化性能 18 3.3 系列1.0G超支化大分子受阻酚抗氧剂的抗氧化性能 22