铝合金表面处理论文学案.doc

摘 要 本论文分为两部分，第一部分为聚天冬氨酸改性的锆转化膜耐蚀性研究；第二部分为具自修复性的杂多酸改性锆系转化膜研究。 （1）X射线光电子能谱（XPS）等方法对膜层耐蚀性、微观形貌及化学组成进行表征，并采用退膜试验、耐水煮试验，抗杯凸试验和转化液稳定性试验对复合转化膜的膜重及附着力，转化液的稳定性进行了测试分析。结果表明：聚天冬氨酸的加入量在0.5~1.0g/L时获得的转化膜耐蚀性最佳，相应的电化学拟合阻抗为64.26kΩ；通过聚天冬氨酸的加入可以改变膜层表面形貌，使得膜层有机物组分碳氧化合物的含量增加；此外聚天冬氨酸也使得膜层更为致密且耐盐水浸泡时间更长，但有机物的加入会使得膜重增加，不利于器材轻量化。通过对XPS数据分析，该复合转化膜主要成分是ZrO2、ZrOF2(2)以钨酸钠、偏钒酸钠、氟锆酸钾为成膜主盐，氟硼酸及硝酸镁为促进剂常温下利用浸渍法在铝合金表面制备了具自修复性的杂多酸改性锆系转化膜。实验同时研究了转化液pH值，转化温度及转化时间对钒锆复合膜层耐蚀性的影响。通过重铬酸钾点滴试验、电化学工作站、XPS、场发射扫描及能谱（EDS）等测试手段研究了不同氧化剂添加后膜层的微观形貌及耐蚀机理。结果表明：双氧水和钨酸钠可以增加钒锆转化膜的耐蚀性，其中钨酸钠表现出来的自修复性能更加明显；过硫酸铵和高锰酸钾会降低钒锆转化膜的耐蚀性，并且膜层没有表现出期望的自修复性能。在实验条件优化的基础上对钨钒杂多酸锆系转化膜进行了详细的XPS检测结果表明关键词：；；；；Abstract This paper includes two parts. The first part was a study on a polyaspartic modified on aluminum zirconium-based conversion. The second part was about self-repairing tungstovanadate-zirconium conversion coating. (1) In this work, the composite conversion coating on aluminum alloys was performed by immersion in a solution containing polyaspartic. Spot test, electrochemical workstation, scanning electron microscopy, X-ray photoelectron spectroscopy (XPS) and other methods detected coating corrosion resistance, chemical composition and microstructure characterization, by adopt Stripping, water cook test, anti-Cupping test and conversion solution stability test discussed conversation coatings weight and adhesion, stability of conversion liquid composite. The results showed that: when polyaspartic added in the amount of 0.5~1.0g/L obtained the coating was of good corrosion resistance, corresponding electrochemical impedance fitting 64.26kΩ, polyaspartic acid by the addition may be changed coating’s surface morphology, so that the content of the coating component of organic matter and oxygen compounds increases; in addition polyaspartic also makes the film more dense salt water soak longer, but the addition of organic matter will make the film weight increases, It is not conducive to lightweight equipment. By XPS data analysis, the m