基于病毒的锂离子电池电极的Co3O4纳米线的合成教材.ppt

Virus-Based Synthesis of Co3O4 Nanowires for Li-ion Battery Electrodes Lion Team Past By The nucleic-acid ‘system’ that operates in terrestrial life is optimized (through evolution) chemistry incarnate. Why not use it ... to allow human beings to sculpt something new, perhaps beautiful, perhaps useful, certainly unnatural. ——Roald Hoffmann Now and Future Outline Properties and Applications of Co3O4 Process to get viral Co3O4 nanowires Characterization of viral Co3O4 nanowires The assembled monolayer of Co3O4 nanowires/Li cell Outlook 1. Properties and Applications of Co3O4 Mixed-valence (CoO?Co2O3) Spinel structure Co2+ Co3+ O2- Applications The?Li-ion Battery?anode material Supercapacitor Hard alloy Varistor ceramics Inorganic Pigments Catalyst 2. Virus-Based Synthesis WHAT? Virus-based synthesis just as its name implies use virus as template for constructing and organizing the nanostructure WHY? The inherent capabilities of molecular recognition and self-assembly M13 ?Phage 3.Process to get Co3O4 nanowires Modify p8 protein through additions in the M13 genome(M13-E4) Incubated the M13-E4 virus templates in aqueous CoCl2 solution(1 mM) Reduction with NaBH4 Spontaneous oxidation in water M13 Virus M13-E4 Virus Co3O4 nanowires Modify Incubated Aqueous CoCl2 solution Reduction with NaBH4 M13 Virus With Co Spontaneous oxidation Progress Map N terminus Tetra glutamate EEEE- 4. Properties Outlook Semiconductor Magnetic nanowires Separate O2 from H2 …………. References Ki Tae Nam et al. Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes. Science 312, 885 (2006) Byung Yang Lee et al. Virus-based piezoelectric energy generation. Nature Nanotechnology 7, 351–356 (2012) Chuanbin Mao et al. Virus-Based Toolkit for the Directed Synthesis of Magnetic and Semiconducting Nanowires. Science 303, 213 (2004) Woo-Jae Chung et al. Biomimetic self-templating supramolecular structures. Nature 478, 364–368 (20 October 2011) Lü Y H, Qiu F, Wang Q Z.