表面张力及消泡剂剖析.ppt

BYK-Chemie,Shanghai BYK-Chemie,Shanghai * 消泡剂 消泡原理 消泡剂的分类 * STOKES方程式 V ~ r2 h 气泡越小 上升速度越慢 粘度越大 气泡上升速度越慢 V = 气泡上升速度 r = 气泡半径 h = 介质粘度 * 消泡剂和脱泡剂的作用场合 气泡在表面 消泡剂 气泡在湿涂膜内 脱泡剂 涂料粘度小时 涂料粘度大时 * 聚二甲基硅氧烷 (CH3)3 Si O Si O Si (CH3)3 CH3 CH3 x 流平 表面平滑 消泡 锤纹效果 相容 不相容 X * 有机改性聚硅氧烷 CH3 R2 CH3 R1 x y (CH3)3Si O Si O Si O Si(CH3)3 z R1=聚醚 R2=烷基 流平 表面平滑 消泡 锤纹效果 相容 不相容 X 丙烯酸系列消泡剂 CH2 C C=O R1 n O R2 * 流平 表面平滑 消泡 锤纹效果 相容 不相容 X * 表面张力差异引起表面流动 缩孔 贝纳德窝 举例说明油墨表面张力与基材表面张力30mN/m2不同情况 * 油墨体系表面张力 油墨1表面张力33mN/m2 油墨2表面张力29mN/m2 油墨3表面张力25mN/m2 出现情况 无底材润湿 流动性差 良好底材润湿 底材润湿过好 流动性及流平性差 相应使用助剂种类 降低表面张力，用低活性有机硅或丙烯酸类 如有需要，用低活性有机硅或丙烯酸改善流动和流平 减少使用有机硅用量从而增加表面张力改善流动和流平性 * 底材润湿性-涂料应用的先决条件 涂料表面张力大于底材表面张力 --涂料失去润湿 涂料表面张力小于底材表面张力 --涂料润湿铺展 * 涂料的表面张力高些好还是低些好？ * 关于消泡剂结论 在满足底材润湿和控制表面流动的前提下, 涂料的表面张力应尽可能地高! * Directly after the formation, the gas bubbles rise through the liquid to reach the surface. According to stokes Law, the rising velocity is dependent upon the radius (r) of the bubbles and upon the viscosity (h)of the liquid. This means that small bubbles rise very slowly and so it is very difficult to defoam an ink which contains micro-foam. Also the viscosity of the ink plays an important role. Since the velocity is inverse proportional to the viscosity, an increase in viscosity will make it more difficult to defoam. This factor plays a major role in the defoaming of screen inks, but also in water based liquid inks, since these are printed at higher viscosity compared to solvent based systems. * One often refers to defoaming whenever the romoval of gas bubbles from a layer is required; however, distinctions between defoaming and deaerating are sometimes made. To begin with, the gas bubbles must somehow reach the surface. This very process of reaching the surface is referred to air release or deaeration. On the other hand, the destruction of air bubbles on the surface represents the actual defoaming. This strict differentation is not always possib