聚苯胺碳纳米纤维复合材料的制备及电容性能..docVIP

[研究论文] 聚苯胺/碳纳米纤维复合材料的制备及电容性能 张雷勇1 何水剑1 陈水亮1 郭乔辉2 侯豪情1,* (1江西师范大学化学化工学院, 南昌 330022； 2中国科学院长春应用化学研究所, 长春 130022) 摘要: 采用原位聚合法制备了聚苯胺/碳纳米纤维(PANI/CNF)复合材料, 用傅里叶变换红外(FT-IR)光谱、高温微量热天平(TGA)、扫描电镜(SEM)和孔分布及比表面积测定仪研究了复合材料的表面官能团、热性能、表面形貌及比表面积, 并运用循环伏安(CV)法和计时电位法测试了PANI/CNF布作为电极材料的电化学性能. 研究结果表明: PANI/CNF复合材料具有粗糙的毛刺结构, PANI沿碳纳米纤维均匀分布; PANI/CNF电极氧化还原反应的可逆性良好; 在100 mA·g-1电流密度下, 当PANI含量为44.4%(W)时复合材料比电容量高达587.1 F·g-1, 比能量为66.1 Wh·kg-1, 电流密度为800 mA·g-1时比功率可达1014.2 W·kg-1; 在5A·g-1的电流密度下, 1000次循环充放电后, 复合材料的比电容量衰减28%. PANI/CNF复合材料具有良好的导电性和快速充放电能力, 是一种优良的电容器电极材料. 关键词: 碳纳米纤维布; 聚苯胺; 电化学性能; 比电容量; 复合材料 中图分类号: O646 Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofibers Composite Materials ZHANG Lei-Yong1 HE Shui-Jian1 CHEN Shui-Liang1 GUO Qiao-Hui2 HOU Hao-Qing1,* (1College of Chemistry and Chemical Engineering , Jiangxi Normal University, Nanchang 330022, P. R. China; 2Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun, P. R. China) Abstract: Polyaniline/Carbon Nanofiber (PANI/CNF) composite materials were prepared by in-situ polymerization. The composite materials were characterized by Fourier transform infrared (FT–IR) spectroscopy, Thermogravimetric analyzer (TGA), scanning electron microscopy (SEM) and Brunauer-Emmelt-Teller analysis . Cyclic voltammetry (CV) and galvanotactic charge/discharge methods were used to study the electrochemical properties of the PANI/CNF composite materials. Results showed that composite materials presented rough surface with burry structure of PANI uniformly distributed on the CNF by this method. The composite materials showed good reversibility of redox reaction as electrodes. The specific capacitance of PANI/CNF containing 44.4% PANI was 587.1 F·g-1 , the specific energy was 66.1 Wh·kg-1 at a current density of 100 mA·g-1, and the specific power was 1014.2 W·kg-1 at a current density of 800mA·g-1. Moreover, the specific capacitance of PANI/CNF only decreased 28% after 1000