ppt课件-organic chemistry- city universityof new york（有机化学-纽约城市大学）.pptVIP

Carbonyls Carbonyls can also fragment. Propose a mechanism for this transformation Carbonyls Or alternatively, you could push arrows other way to methyl radical Aldehydes and Ketones Why might you expect 43 be larger then 113? Aldehydes and Ketones Aldehydes and Ketones Who’s to say you can’t draw it as a radical mechanism too? Carboxylic Acids Characteristic fragmentation patterns are ?-cleavage to give the ion [CO2H]+ with m/z 45. McLafferty rearrangement. Carboxylic Acids Mass spectrum of butanoic acid. What are the fragmentations at 60 and 45? Carboxylic Acids Mass spectrum of butanoic