ppt课件-studyofthepossibilityofcn-backgroundincoallsky.pptVIP

Mn12ac as Single Molecular Magnet Overall antiferromagnetic coupling is realized from temperature dependance of ?mT (succesptibility product) Value of ?mT at room temperature is smaller than expected for uncoupled spins indicated antiferromagnetic coupling Maximumum ?mT observed at at low temperature (55.6 emu mol-1 K) is close to the value for spin S = 10 (Gatteschi and Sessoli, Angew. Chem 2003) 19.4 emu mol-1 K(observed) 31.5 emu mol-1 K (expected for uncoupled spins) Mn12ac as Single Molecular Magnet Evidence for magnetic anisotropy along easy axis comes from single crystal mag