ppt课件-c h m434 f1206 f s o l i d s t a t e m a t e r i a l s c h e m i s t r y（c h m434 f1206 f s o l i d s t t e m t e r l s c h e m r i s t y）.pptVIP

BONDING AND ELECTRONIC STRUCTURE IN MAGNESIUM DIBORIDE - DOS - THINKING ABOUT ORIGIN OF SUPERCONDUCTIVITY IN MgB2 SUPERCONDUCTIVITY IN MgB2 AT 39K A SENSATIONAL AND CURIOUS DISCOVERY Metallic MgB2 known 1953, direct synthesis from Mg/B Akimitsu Nature 2001, 410, 63 Tc of 39K, surprising - Tc Nb3Ge 23K, LaxSr1-xCuO4 40K, YBa2Cu3O7 90K Graphitic B22- sheets sandwiching hcc Mg2+ layers Isoelectronic graphite is not a superconductor - only when doped at 5K? Strong p-p bonding interactions between B6 rings and Mg p-p stabilized wrt s-?* of graphitic-like B22- sheets Cooper pairs from excitation o