ppt课件-defining solutions- n d s u（定义解决方案- n d s u）.pptVIP

REACTION KINETICS General Concepts Michaelis-Menten kinetics Surface Area Critical to rate calculations and predictions Geometric area estimation (often requires averaging or stochastic theory) BET measurements, usually w/ N2 (4? compared to 3? for H2O) Surface roughness (BET/Geometric): SR = 5 - 12 for fresh ground silicate SR = 300 - 2000 for deeply weathered natural silicates Feldspar dissolution kinetics and composition Silicate dissolution kinetics and pH Silicate weathering reactions Conclusions: silicate weathering Natural weathering rates in soils are 102 to 105 slower than exp. rat