干法制备羧甲基淀粉毕业论文.doc

2015届毕业论文 题 目 干法制备羧甲基淀粉 专业班级 学 号 学生姓名 刘玉洁 学 院 化工与制药学院 指导教师 指导教师职称 完成日期： 2015 年 6 月 日  干法制备羧甲基淀粉 Preparation of Carboxymethyl Starch 学生姓名 刘玉洁 指导教师 欧阳贻德/金士威 羧甲基淀粉（CMS)是一种非常重要的阴离子型醚化淀粉，其用途十分广泛。社会对其需求量的，对羧甲基淀粉的研究已 以玉米淀粉为原料，采用干法制备高取代度的羧甲基淀粉。反应分为碱化和醚化2个阶段，以异丙醇为溶剂，氢氧化钠为碱化剂，氯乙酸钠为醚化剂，对羧甲基淀粉工艺进行了研究。考察了碱化温度、碱化时间、醚化温度、醚化时间对羧甲基淀粉取代度的影响，最终确定最佳的碱化温度为35℃，碱化时间为60min，醚化温度为70℃，醚化时间为150min，在此条件下制得的羧甲基淀粉的取代度为0.32，产品的外观得到改善，淀粉糊的黏度稳定性得到加强。 关键词：羧甲基淀粉；干法；制备；取代度；醚化  Abstract Carboxymethyl starch (CMS) is an important kind of anionic etherified starch, and is widely applied in many areas. With the increasing demand of society, people have paid more attention to study carboxymethyl starch gradually, which has become a hot spot in recent years. Currently, there is a low degree of substitution, the viscosity instability of the starch paste, poor appearance and other shortcomings on the industrial production of carboxymethyl starch and therefore that greatly limits its application. Highly substituted carboxymethyl starch was produced by dry method used corn starch as raw material. The process was made up of two steps, that was the alkalizing reaction and the etherifying reaction. The isopropyl alcohol （whose volume fraction was 60%)was used as a solvent, alkalizing agent was sodium hydroxide and the etherifying agent was sodium chloroacetate. The effects of the alkalizing temperature and reaction time, the etherifying temperature an