合成丙二醇丁醚工艺初步设计.docx

摘 要由于乙二醇醚具有毒性，所以其正在被丙二醇醚逐步取代，并广泛应用于油墨、皮革着色剂、涂料稀释剂、乳化液稳定剂等众多工业领域。但目前国内丙二醇醚的产量和质量还不能满足市场需求，所以迫切需要改善丙二醇醚的生产工艺流程。 本文介绍了丙二醇丁醚在国内外的研究动态、目前的水平以及未来的发展方向，归纳了合成丙二醇丁醚的具体方法，分析了目前国内外生产该产品的工艺类型，如釜式反应器、连续管式反应器、Buss回路反应器、Press式反应器、催化精馏反应器等，并总结了各种反应器的优点及其不足之处，然后针对Press式外循环反应器生产流程做出了具体的车间工艺流程设计。丙二醇醚的生产工艺设计如下：根据生产工艺条件，采取以环氧丙烷和丁醇为原料，采用固体碱为催化剂，在温度为120～140 ℃，压力为0.2～0.5 MPa，反应时间为2.0～4.0 h，摩尔比为丁醇 : 环氧丙烷 = 2.5 : 1的条件下，合成丙二醇丁醚。设计年产3000吨的丙二醇丁醚车间，通过物料衡算和能量衡算，确定反应釜容积、筒体高度及直径，确定填料塔塔板数、填料高度以及塔径大小，确定浮阀塔的塔高、塔径、塔板数以及溢流堰高度、堰高等。并通过核算完成设备选型，画出带控制点的工艺流程图及反应主设备图，精馏分离图等。希望通过本次设计，能够为进一步优化我国丙二醇醚的生产工艺做出一点贡献。关键词：丙二醇丁醚；环氧丙烷；丁醇；外循环AbstractSince glycol ethers are toxic, so it is being gradually replaced by propylene glycol ethers, and widely used in inks, leather colorants, paint thinner, emulsion stabilizers and many other industrial fields. But the yield and quality of domestic propylene glycol ethers can not meet the market demand, there is an urgent need to improve the production process of propylene glycol ethers.This paper described the research trends of propylene glycol butyl ether at home and abroad, the current level and future direction of development, summarized the specific method for the synthesis of propylene glycol butyl ether, and the current types of domestic and foreign production process of the product was analyzed, such as a tank reactor, continuous tubular reactor, Buss loop reactor, Press loop reactor, catalytic distillation reactors and so on. Moreover, the various advantages and disadvantages of the reactors was summarized, and then directs at the reaction production process of press external loop reactor to make a specific workshop process design.Propylene glycol ether production process design is as follows: according to the production process conditions, adopting with propylene oxide and butyl alcohol as raw material, the solid alkali as the catalyst, under the condition of the temperature is 120～140 ℃, pressure is 0.2～0.5 MPa, reaction time is 2.0～4.0 h, molar ratio of butyl alcohol