PSA的理论及制造培训教程文件.pptVIP

壓克力系PSA( Acrylic PSA) Acrylic PSA Composition: Main Monomer: 50-90% Modifying Monomer: 10-40% Monomer with Functional groups: 2-20% 4 Types of Acrylic PSA Solutions Aqueous Emulsion Hot Melts 100% Reactive Solis Physical Properties depend on: 1. Tg 2. Monomer Composition 3. MW MWD 4. Crosslinker Crosslinking Density 5. Additives: Tackifier, Plasticizer, Filler Fox Equation 1/Tgp = W1/Tg1 + W2/Tg2 +……. Tgp : glass transition temperature of copolymer Tg1 , Tg2 : glass transition temperature of monomer 1 2 W1 , W2 : weight fraction of monomer 1 2 2 Basic Approaches of Crosslinking : 1.Functional groups are introduced along the polymer chain, and a multifunction additive capable of reacting with the pendant functional groups is introduced later. 2. Multiple functionalities capable of interaction are introduced into the polymer chain providing the sites for intermolecular crosslinking. Functional Groups of Monomer: 1. Carboxylic Groups 2. Hyrdoxy 3. Epoxyl 4. N-methylolamide 5. aldehyde 6. Isocyanate 7. Others 常用之架橋劑: 1. Polyfunctional Isocyanate 2. Melamine Resin 3. Epoxyl Resin 4. Metal Chelating Agent 5. Polyaziridine Radation Curable Acrylic System (UV and EB System) (A) Acrylic Hot Melts (a) Non Reactive Acrylic Hot Melt PSA (b) EB Curable System (c) UV Crosslinkable Acrylic Hot Melt (B) Solvent Free Systems (a) EB Curable System (b) UV Curable System 矽橡膠PSA( Silicone PSA) 2 major Component: Polymer (Gum): high MW Polydimethyl- siloxane or Polydimethyldiphnyl- siloxane Resin: 3 Dimensional silicatestructure endcapped with trimethylsiloxy groups(OSiMe3) Cure Chemistry 1. Condensation Type 2. Addition Type Block Copolymer: Thermoplastic A-B-A Block Copolymer: SIS SBS SEBS SEPS Application: Sol