万吨聚氯乙烯车间工艺设计.doc

毕业设计说明书 悬浮聚合法年产30万吨聚氯乙烯 车间工艺设计 学生姓名： 学号： 学 院： 专 业： 指导教师： 2012年6月日 悬浮聚合法年产30万吨聚氯乙烯车间工艺设计 摘要 本聚氯乙烯的、，确定了聚氯乙烯的生产工艺。物料衡算、热量衡算设备选型、车间经济核算。防火防爆防雷和三废的处理回收等方案进行了简单的阐述。 关键词：聚氯乙烯，悬浮聚合，反应釜， The process design for PVC workshop of suspension polymerization with annual output of 300000 tons Abstract The properties, application, development and the technology progress of PVC were summaried in this paper. After the influence factors of synthesis process discussed, the production of acetic anhydride process route and related parameters are determined, and the material balance and heat balance of main equipments were calculated. Based on this, the equipments selection, workshop layout and economic accounting were accomplished. In addition, the protection of fire, lightning, poison and three wastes treatment recovery plan were simply discussed. Finally the process flow chart with control point, the figure of main equipments and workshop layout were drawed. Keywords: PVC；suspension polymerization；agitated reactor；process design 目 录 1 绪论………………………………………………………………………………1 1.1 聚氯乙烯简介…………………………………………………………………1 1.2 聚氯乙烯的发展状况…………………………………………………………1 1.3 国内外聚氯乙烯悬浮聚合的工艺进展………………………………………1 1.3.1 国内聚氯乙烯悬浮聚合的工艺进展…………………………………………2 1.3.2 国外聚氯乙烯悬浮聚合的工艺进展…………………………………………3 1.4 聚合工艺实践方法……………………………………………………………5 1.4.1 本体聚合生产工艺……………………………………………………………5 1.4.2 乳液聚合生产工艺……………………………………………………………5 1.4.3 悬浮聚合生产工艺……………………………………………………………5 1.5 悬浮聚合生产工艺的两种操作方法的比较…………………………………6 1.5.1 连续式操作……………………………………………………………………6 1.5.2 间歇式操作……………………………………………………………………7 1.6 氯乙烯悬浮聚合生成聚氯乙烯过程中的影响因素…………………………7 1.6.1 纯水的影响……………………………………………………………………7 1.6.2 乙炔的影响……………………………………………………………………7 1.6.3 高沸物的影响………………………………………………………………8 1.6.4 聚合体系中氧的影响………………………………………………………8 1.6.5 聚合体系中铁的影响………………………………………………………8 1.6.6 分散剂的影响………………………………………………………………8 1.6.7 引发剂的影响………………………………………………………………9 1.6.8 涂釜剂的影响………………………………………………………………9 1.6.9 调节剂的影响