从相图到材料成份设计培训教案.ppt

从相图到材料成分设计： Composition rules of amorphous alloys and quasicrystals 董Dong 闯Chuang Dalian Univ. of Tech., China Zr-Ti-Ni Icosahedral cluster derived from Al13Fe4 Zr-Ti-Ni Binary QC composition rule Formation rule of ternary quasicrystals compositions e/a Tg (K) Tx (K) ?Tx (K) Tm (K) Tl (K) Tg/Tm Tg/Tl γ ? ?Tl (K) ?Tg (K) Zr58.6Al15.4Ni26 1.34 707 789 82 1188 1274 0.595 0.555 0.398 485 567 Zr57.5Al16.9Ni25.6 1.37 721 801 80 1186 1280 0.608 0.563 0.400 479 559 Zr55.8Al19.4Ni24.8 1.42 735 805 70 1184 1277 0.621 0.576 0.400 472 542 Zr54Al22Ni24 1.47 751 813 62 1183 1284 0.635 0.585 0.400 471 533 Zr53Al23.5Ni23.5 1.5 771 822 51 1180 1288 0.653 0.599 0.401 466 517 Zr58.4Al20.8Ni20.8 1.5 720 776 56 1184 1289 0.608 0.559 0.386 513 569 Zr60Al20Ni20 1.5 713 766 53 1183 1294 0.603 0.551 0.382 528 581 Zr63Al185Ni18.5 1.5 702 747 45 1193 1315 0.588 0.534 0.370 568 613 The e/a-criteria for the largest GFA of Zr-Al-Co alloys eutectic (a) (b) Suction-cast Zr-Al-Co rods with 3mm in diameter BMG-formation e/a span: 1.30~1.50 e/a=1.5 series Al-Ni4Zr9 series (a) (b) DSC (a) and DTA (b) traces of the Zr9Co4-Al e/a-variant and 1.5 e/a-constant BMGs. ?Tx ? ?Tg ?Tl (a) (b) Thermal stability and GFA (Zr-Al-Co): e/a Compositions Tg Tx ?Tx Tg/Tm Tg/Tl γ ?Tg 1.43 Zr55Al20Co25 Reference 764 839 75 0.621 0.583 0.405 546 1.5 Zr53Al23.5Co23.5 783 849 66 0.637 0.590 0.404 537 Application to Zr-Al-Cu: Cu56Zr44 Cu61.8Zr38.2 Cu82.8Al17.2 No. Composition (at%) e/a Ra (nm) Tg (K) Tx (K) △Tx (K) Tm (K) Tl (K) Tl-Tm (K) Tg/Tm Tg/Tl Cf1 Cu60.3Zr37.2Al2.5 1.236 0.1403 733 794 61 1151 1185 34 0.637 0.619 C11 Cu59.6Zr36.9Al3.5 1.254 0.1403 740 802 62 1157 1181 24 0.640 0.627 Cf2 Cu58.7Zr36.3Al5 1.281 0.1404 748 803 55 1159 1179 20 0.645 0.634 Cf3 Cu57.8Zr35.7Al6.5 1.309 0.1404 745 796 51 1160 118