Decoupling of Iron and Phosphate in the Global Ocean全球铁和磷酸盐的解耦.pptVIP

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Decoupling of Iron and Phosphate in the Global Ocean全球铁和磷酸盐的解耦.ppt

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Decoupling of Iron and Phosphate in the Global Ocean Payal Parekh MIT/WHOI Joint Program April 18, 2003 In collaboration with Mick Follows, Ed Boyle and John Marshall Thesis Aims Develop a mechanistic model of iron cycling to: reproduce observed [Fe] predict rates of biogeochemical processes understand controls on Fe in upwelled waters gain insight on decoupling of Fe and PO4 Motivation: Understand iron’ s role in possible pCO2 drawdown. High Nutrient, Low Chlorophyll Regions Chlorophyll Distribution Could Lack of Iron be the Culprit? Sources of Iron to surface waters: Upwelling Aeolian Dust Flux Link between dust flux and pCO2? Iron Addition Experiment Why are Fe and PO4 decoupled? Iron Biogeochemistry Iron Observations Is it possible to reproduce and understand controls on observed deep water Fe distributions? Perform sensitivity tests to constrain rates of biogeochemical processes using an idealized multi box model Test iron parameterization in the MITGCM, resolve intrabasinal differences and vertical profile of iron Box Model Simulations Volume transport chosen to fit Radiocarbon, Broecker/Peng (86,87) Tracers: PO4, DOP, Fe Biological Uptake: μ*[Fe/(Fe+Ks)] Michaelis-Menten kinetics – Fe, light limited Iron Parameterization K= binding strength of ligand Log(K) ranges 9.5-13.2 FeL=K[Fe’][L’] LT=L’+FeL LT = 1 nM, based on Rue/Bruland (1995) and others Results: Complexation Case Summary: Box Model Results Iron parameterization successfully reproduces deep water Fe gradients Sensitivity study constrains scavenging rate over wide range of K (ligand binding strengths). Explorations with an Ocean General Circulation Model Same parameterization as in box model Forced seasonally with Gao et al. (2001) dust flux estimate Modeled Fe Fe exceeds solubility (Liu and Millero, 2002) in surface waters Successfully reproduces observed Fe gradients at depth Observations: PO4 Modeled PO4 Fe limitation term [μ*(Fe/Fe+Ks)] successfully reproduces HNLC region Previously, model