在压敏电阻氧化锌氧化铜内中添加氧化铬,氧化铋,氧化镍对显微结构与电流电压特性的改变.docxVIP

Research Article研究報告Microstructure and Current-voltage Characteristics of (ZnO-CuO) Varistor System in the Presence of Additive Oxides, Cr2O3, Bi2O3?and NiO在壓敏電阻氧化鋅-氧化銅內中添加氧化鉻, 氧化鉍, 氧化鎳對顯微結構與電流-電壓特性的改變S.E. Mansour,?O.A. Desouky,?S.M. Negim?and?W.A. Kamil作者：馬來西亞聖英大學(University Sains Malaysia )翻譯：晟銘電子 技術長 達安企業 科學顧問-邱耀弘博士，國立台灣科技大學機械所材料科學組畢業ABSTRACT摘要The microstructure, electrical properties and density of ZnO-based varistor ceramics with different CuO content prepared by ball milling and sintered at (900~1200°C) were investigated. The nonlinear coefficient (α) and density increase with increasing CuO content. The presence of a liquid phase facilitated the sintering process and developed atomically interfaces, uniform intergranular phase required for non-linear conduction. The presence of Cr2O3?in group (II) absent of grain growth (inhibition of grain growth) and enter in solid solution with ZnO.?X-ray diffraction?analysis of sintered samples reveals no formation of new phases, but lattice constants of the phases were changed after sintering.利用球磨法添加不同重量的氧化銅到現有的氧化鋅為基礎的壓敏電阻陶瓷系統中，然後燒結(900~1200°C)後觀察其顯微結構, 電子特性以及密度。氧化銅的量增加造成非線性係數(α)與陶瓷體密度的值增加。由於燒結過程液相出現在晶界，其提供原子進出的便利通道、均勻的晶界相，這是非線性傳導的要求。實驗發現添加氧化鉻該第2組(II)的晶粒不成長(被抑制了)同時與氧化鋅發生固溶反應。以X光繞射分析燒結後的試片沒有發現新的相，但在燒結後的相其晶格常數改變。How to cite this article 如何引用本文章S.E. Mansour, O.A. Desouky, S.M. Negim and W.A. Kamil, 2011. Microstructure and Current-voltage Characteristics of (ZnO-CuO) Varistor System in the Presence of Additive Oxides, Cr2O3, Bi2O3?and NiO.?Current Research in Chemistry, 3: 29-48. DOI:?10.3923/crc.2011.29.48?URL:?/abstract/?doi=crc.2011.29.48Received:?November 10, 2010;?Accepted:?November 14, 2010;?Published:?April 22, 2011INTRODUCTION簡介Varistors are materials with nonlinear current-voltage characteristics. They are used both as protecting devices against over voltages in electronic and industrial equipments and as surge arrestors (Souza et al., 2003). Commercial varistors used in protection systems are based on SiC (silico