高拉速中碳钢连铸保护渣的开发.docVIP

高拉速中碳钢连铸保护渣的开发 陈 敏1，李学慧1，2 (1.东北大学材料与冶金学院，辽宁 沈阳 110004；2.鞍钢实业公司，辽宁 鞍山 114000) 摘 要：结晶器保护渣是连铸生产过程中重要的辅助材料，其性能优劣对连铸工艺顺行及铸坯质量产生重要的影响。中碳钢自身的凝固特点使其对连铸保护渣提出了更严格的要求。本研究根据中碳钢连铸的特点，研究了原料组成对保护渣性能的影响规律，并在此基础上开发了中碳钢连铸系列保护渣。研究结果表明，在保护渣中配入B2O3、Li2O、MnO等特殊组分，不仅降低保护渣的析晶温度和转折温度，而且促使固态结晶渣膜晶粒细小，因此可以避免保护渣熔渣在冷凝过程中析出高熔点固相，使结晶器内靠近铸坯表面的渣膜为液态，确保铸坯表面的润滑效果，同时又可使靠近结晶器壁的渣膜形成结晶状态以达到减缓和均匀传热的效果。在实验室研室研究的基础上，本研究开发的系列连铸保护渣在实际生产中获得了良好的使用效果，有效地促进了铸坯质量的提高。 关键词：连铸，保护渣；理化性能；结晶行为；中碳钢 Development of Mould Powder for High Speed Continuous Casting of Medium-Carbon Steel Slab CHEN Min1 Li Xue-Hui1，2 (1. School of materials and metallurgy, Northeastern University, Shenyang, Liaoning, 110004 China; 2. Industry Co. Ltd, Anshan Iron and Steel Group Corporation, Anshan, Liaoning, 114000China) Abstract: Mold powder as an important supplemental materials for continuous casting, its properties determines the slab quality directly, and more strict requirements are necessary for the continuous casting of medium-carbon steel slab for its solidification characters. The present work studied the effect of composition on properties of mould powder and developed a serious products for continuous casting of medium-carbon steel. The results showed that both crystallization and breaking temperatures were decreased, and the grain size in the solidified flux film was also deceased by inducing some special component such as B2O3, Li2O, MnO. Consequently, by preventing precipitation of high melting phases during cooling process, liquid flux film on the surface of solidified shell was formed to insure the greasing performance, and at the same time, the crystallized flux film was formed on the side of mould wall to maintain weak and homogeneous heat transfer. Based on the above studies of laboratory work, a serious products of mold powder was developed , and the practical application of the serious products showed good performance and the slab quality was effectively improved for continuous casting of medium-carbon steel. Key wor